Performance increase of microfluidic formic acid fuel cell using Pd/MWCNTs as catalyst

被引:56
作者
Morales-Acosta, D. [1 ]
Rodriguez, H. [1 ]
Godinez, Luis A. [1 ]
Arriaga, L. G. [1 ]
机构
[1] Ctr Invest & Desarrollo Tecnol Electroquim, Pedro Escobedo 76703, Queretaro, Mexico
关键词
Microfluidic fuel cell; Formic acid; Palladium nanoparticles; Carbon nanotubes; WALLED CARBON NANOTUBES; LAMINAR-FLOW; PD; ELECTROOXIDATION; OXIDATION; NANOPARTICLES; ELECTRODES; PALLADIUM; FILMS;
D O I
10.1016/j.jpowsour.2009.10.007
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This paper shows that the combination of an O-2 saturated acidic fluid setup (O-2-setup) and a composite of Pd nanoparticles supported on multiwalled-carbon nanotubes (Pd/MWCNTs) as anode catalyst material, results in the improvement of microfluidic fuel cell performance. Microfluidic fuel cells were constructed and evaluated at low HCOOH concentrations (0.1 and 0.5 M) using Pd/V XC-72 and Pd/MWCNTs as anode and Pt/V XC-72 as cathode electrode materials, respectively. The results show a higher power density (2.9 mW cm(-2)) for this cell when compared to the value reported in the literature that considers a commercial Pd/V XC-72 and 3.3 mW cm(-2) using a Pd/MWCNTs with a 50% less Pd loading than that commercial Pd/V XC-72. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:1862 / 1865
页数:4
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