Reactions of nickel(0) with organochlorides, organobromides, and organoiodides: mechanisms and structure/reactivity relationships

被引：49

作者：

Greaves, Megan E. ^{[1
,2
]}

Johnson Humphrey, Elliot L. B. ^{[1
]}

Nelson, David J. ^{[1
]}

机构：

[1] Univ Strathclyde, WestCHEM Dept Pure & Appl Chem, 295 Cathedral St, Glasgow G1 1XL, Lanark, Scotland

[2] AstraZeneca, Chem Dev Pharmaceut Technol & Dev, Operat, Macclesfield SK10 2NA, Cheshire, England

来源：

CATALYSIS SCIENCE & TECHNOLOGY | 2021年 / 11卷 / 09期

基金：

英国工程与自然科学研究理事会;

关键词：

Substrates - Catalysis - Organic compounds - Phosphorus compounds - Nickel compounds;

D O I：

10.1039/d1cy00374g

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The reactions of nickel(0) complexes with organohalides have been reviewed. The review is divided according to the class of ligand that is present on nickel: phosphine, N-heterocyclic carbene, or bidentate nitrogen ligand. The preferred mechanism of reaction is often determined by a delicate balance of ligand and substrate structure, and relatively small changes can lead to large differences in behaviour. This will have an impact on the progress of catalytic reactions that use organohalide substrates, and may influence ligand selection and/or the scope and limitations of the reaction.

引用

页码：2980 / 2996

页数：17

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