An easy co-casting method to synthesize mesostructured carbon composites with high magnetic separability and acid resistance

被引:16
作者
Guo, Limin [1 ]
Zeng, Shaozhong [1 ]
Li, Jiangtian [1 ]
Cui, Fangming [1 ]
Cui, Xiangzhi [1 ]
Bu, Wenbo [1 ]
Shi, Jianlin [1 ]
机构
[1] Chinese Acad Sci, Shanghai Inst Ceram, State Key Lab High Performance Ceram & Superfine, Shanghai 200050, Peoples R China
基金
美国国家科学基金会;
关键词
ORDERED MESOPOROUS CARBONS; MOLECULAR-SIEVES; FACILE SYNTHESIS; SURFACE FUNCTIONALIZATION; CRYSTALLINE WALLS; SILICA MATERIALS; HOLLOW SPHERES; CATALYST; TEMPLATE; NANOPARTICLES;
D O I
10.1039/b906776k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Magnetic mesoporous carbon composites with high surface areas and narrow mesopore size distributions were directly replicated from SBA-15 by a simple co-casting method and the amount of incorporated magnetic particles and saturation magnetization value can be easily tuned by changing the added amount of iron source during synthesis. Furthermore, the magnetic mesoporous carbon composites show good acid resistance due to a carbon shell coating structure around the magnetic particles, which is spontaneously formed during the replication process of the mesoporous carbon composites. The characteristics of the as-synthesized magnetic mesoporous carbon composites were examined by X-ray diffraction, N-2 sorption, transmission electron microscopy (TEM), Mossbauer spectroscopy and vibrating-sample magnetometry.
引用
收藏
页码:1926 / 1931
页数:6
相关论文
共 65 条
  • [1] MOSSBAUER STUDY OF FERRIC IONS IN TETRAHEDRAL AND OCTAHEDRAL SITES OF A SPINEL
    ARMSTRONG, RJ
    MORRISH, AH
    SAWATZKY, GA
    [J]. PHYSICS LETTERS, 1966, 23 (07): : 414 - +
  • [2] STUDY OF LOW-TEMPERATURE TRANSITION IN MAGNETITE AND INTERNAL FIELDS ACTING ON IRON NUCLEI IN SOME SPINEL FERRITES, USING MOSSBAUER ABSORPTION
    BAUMINGER, R
    OFER, S
    SEGAL, E
    MARINOV, A
    COHEN, SG
    [J]. PHYSICAL REVIEW, 1961, 122 (05): : 1447 - &
  • [3] Buchel G, 1998, ADV MATER, V10, P1036, DOI 10.1002/(SICI)1521-4095(199809)10:13<1036::AID-ADMA1036>3.0.CO
  • [4] 2-Z
  • [5] Intercalation of Aggregation-Free and Well-Dispersed Gold Nanoparticles into the Walls of Mesoporous Silica as a Robust "Green" Catalyst for n-Alkane Oxidation
    Chen, Lifang
    Hu, Juncheng
    Richards, Ryan
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (03) : 914 - +
  • [6] From microporous to mesoporous molecular sieve materials and their use in catalysis
    Corma, A
    [J]. CHEMICAL REVIEWS, 1997, 97 (06) : 2373 - 2419
  • [7] Controllable and repeatable synthesis of thermally stable anatase nanocrystal-silica composites with highly ordered hexagonal mesostructures
    Dong, Weiyang
    Sun, Yaojun
    Lee, Chul Wee
    Hua, Weiming
    Lu, Xinchun
    Shi, Yifeng
    Zhang, Shicheng
    Chen, Jianmin
    Zhao, Dongyuan
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (45) : 13894 - 13904
  • [8] Synthesis and magnetic properties of mesostructured γ-Fe2O3/carbon composites by a Co-casting method
    Dong, Xiaoping
    Chen, Hangrong
    Zhao, Wenru
    Li, Xia
    Shi, Jianlin
    [J]. CHEMISTRY OF MATERIALS, 2007, 19 (14) : 3484 - 3490
  • [9] Facile synthesis of manganese-loaded mesoporous silica materials by direct reaction between KMnO4 and an in-situ surfactant template
    Dong, XP
    Shen, WH
    Zhu, YF
    Xiong, LM
    Shi, JL
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2005, 15 (06) : 955 - 960
  • [10] A facile route for the preparation of superparamagnetic porous carbons
    Fuertes, AB
    Tartaj, P
    [J]. CHEMISTRY OF MATERIALS, 2006, 18 (06) : 1675 - 1679