A colorimetric and fluorescent turn-on chemosensor for Al3+ and its application in bioimaging

被引：194
作者：
Wang, Yan-Wei [1 ]
Yu, Meng-Xiao [2 ,3 ]
Yu, Yan-Hong [4 ]
Bai, Zhi-Ping [1 ]
Shen, Zhen [1 ]
Li, Fu-You [2 ,3 ]
You, Xiao-Zeng [1 ]
机构：
[1] Nanjing Univ, Nanjing Natl Lab Microstruct, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China
[2] Fudan Univ, Dept Chem, Shanghai 200433, Peoples R China
[3] Fudan Univ, Adv Mat Lab, Shanghai 200433, Peoples R China
[4] Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Peoples R China
来源：
TETRAHEDRON LETTERS | 2009年 / 50卷 / 45期
关键词：
ALUMINUM TOXICITY; ELECTRON-TRANSFER; SENSOR; ION; PH; BORONDIPYRROMETHENE; ACCUMULATION; LUMINESCENCE; DERIVATIVES; RECEPTOR;
D O I：
10.1016/j.tetlet.2009.08.078
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The sensing properties of a boron dipyrromethene derivative 1 containing a N,N-(dimethylamino)styryl group at its cc-position and an aniline moiety at meso-position were investigated by steady-state UV-vis absorption and fluorescence spectroscopy, which were found to exhibit wavelength ratiometric and large fluorescence enhancement in the presence of Al3+ with specific selectivity over other metal ions in aqueous media. Furthermore, confocal fluorescence microscopy experiments demonstrated that I could be used as a fluorescent probe for Al3+ in living cells. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：6169 / 6172
页数：4
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