Bis(μ-6-hydroxypicolinato)-μ-oxo-bis[dipyridinemanganese(III)] monohydrate

被引：10

作者：

Bian, GQ ^{[1
]}

Kuroda-Sowa, T ^{[1
]}

Konaka, H ^{[1
]}

Maekawa, M ^{[1
]}

Munakata, M ^{[1
]}

机构：

[1] Kinki Univ, Fac Sci & Technol, Dept Chem, Higashiosaka, Osaka 577, Japan

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2004年 / 60卷

关键词：

D O I：

10.1107/S0108270104012624

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [Mn-2(mu-O)(C6H3NO3)(2)(C5H5N)(4)].H2O, was isolated from the reaction of 2,6-pyridinedicarboxylic acid with [Mn12O12(CH3COO)(16)(H2O)(4)] in pyridine. The dimanganese complex has twofold symmetry; the Mn-III atoms are bridged by one oxo and two amidate ligands and show compressed octahedral Jahn-Teller distortion. The molecular packing comprises a three-dimensional structure constructed by means of extensive intermolecular interactions, including three kinds of hydrogen bonds and pi-pi interactions.

引用

页码：M338 / M340

页数：3

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