The peripheral and non-peripheral 2H-benzotriazole substituted phthalocyanines: Synthesis, characterization, photophysical and photochemical studies of zinc derivatives

被引：20
|
作者：
Dilber, Gulsev [1 ]
Altunparmak, Hasan [2 ]
Nas, Asiye [1 ]
Kantekin, Halit [2 ]
Durmus, Mahmut [3 ]
机构：
[1] Karadeniz Tech Univ, Mocka Vocat Sch, TR-61750 Trabzon, Turkey
[2] Karadeniz Tech Univ, Dept Chem, TR-61080 Trabzon, Turkey
[3] Gebze Tech Univ, Dept Chem, TR-41400 Gebze, Kocaeli, Turkey
来源：
SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2019年 / 217卷
关键词：
Metallophthalocyanines; Non-peripheral; Peripheral; Photophysical; Photochemical; Singlet oxygen; PHOTOSENSITIZED SINGLET OXYGEN; SUPRAMOLECULAR INTERACTION; QUANTUM YIELDS; INDIUM(III) PHTHALOCYANINES; SILICON PHTHALOCYANINES; ELECTRONIC ABSORPTION; GOLD NANOPARTICLE; METAL-FREE; FLUORESCENCE; INSIGHTS;
D O I：
10.1016/j.saa.2019.01.095
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
In this study, the novel 3-(1H-benzo[d][1,2,3] triazol-1-yl) methoxy substituted novel phthalonitrile compounds (2 and 6) were synthesized. Their non-peripheral and peripheral zinc (II) (3 and 7), manganese (III) (4 and 8) and copper (II) (5 and 9) phthalocyanine complexes were synthesized for the first time. These novel compounds were characterized by elemental analysis and different spectroscopic techniques such as FT-IR, UV-Vis, H-1 NMR, C-13 NMR and MALDI-TOF mass. Also, photochemical and photophysical properties of non-peripheral and peripheral substituted zinc (II) phthalocyanines (3 and 7) were investigated for determination of photodynamic therapy applications of these phthalocyanines. (C) 2019 Elsevier B.V. All rights reserved.
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页码：128 / 140
页数：13
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