Preparation and organic transformation reactions of CpFe(CO)2SCO-3-C6H4-SO2Cl

被引：7

作者：

El-khateeb, M ^{[1
]}

Younes, A ^{[1
]}

机构：

[1] Jordan Univ Sci & Technol, Fac Sci, Dept Chem, Irbid 22110, Jordan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2002年 / 664卷 / 1-2期

关键词：

iron; thiocarboxylate; nucleophilic substitution; structures; sulfonates;

D O I：

10.1016/S0022-328X(02)02015-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of the iron sulfides (mu-S-x)[CpFe(CO)(2)](2) with 3-ClCOC6H4SO2Cl gave the novel organoiron thiocarboxylate complex CpFe(CO)(2)SCO-3-C6H4SO2Cl which contains a free sulfonyl chloride group. This complex reacts with nucleophiles such as R2NH, ArOH and RSH to give stable complexes CpFe(CO)(2)SCO-3-C6H4SO2NR2, CpFe(CO)(2)SCO-3-C6H4SO2OAr, and CpFe(CO)(2)SCO-3-C6H4SO2SR, respectively. The crystal structure of CpFe(CO)(2)SCO-3-C6H4SO2N(CH3)CH2Ph has been determined: space group: P2(1)/c, a = 17.9594(5), b = 9.2395(2), c = 13.4341(4) Angstrom,beta = 95.403(2)degrees, V = 2219.26(10) Angstrom(3) and Z = 4. (C) 2002 Elsevier Science B.V. All rights reserved.

引用

页码：228 / 233

页数：6

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