Highly efficient synthesis of medium-sized lactones via oxidative lactonization: concise total synthesis of isolaurepan

被引：41

作者：

Ebine, Makoto ^{[1
]}

Suga, Yuto ^{[1
]}

Fuwa, Haruhiko ^{[1
]}

Sasaki, Makoto ^{[1
]}

机构：

[1] Tohoku Univ, Grad Sch Life Sci, Lab Biostruct Chem, Aoba Ku, Sendai, Miyagi 9818555, Japan

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2010年 / 8卷 / 01期

关键词：

CYCLIC ETHERS; SELECTIVE OXIDATION; POLYCYCLIC ETHERS; MEDIUM-RING; ENANTIOSELECTIVE SYNTHESIS; CONVERGENT SYNTHESIS; HYDROGEN-TRANSFER; DIOLS; ALCOHOLS; PALLADIUM;

D O I：

10.1039/b919673k

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A catalytic amount of TEMPO in the presence of PhI(OAc)(2) effected oxidative lactonization of 1,6- and 1,7-diols, directly affording seven- and eight-membered lactones, respectively, in good yields.

引用

页码：39 / 42

页数：4

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