Anodic stripping voltammetric determination of total lead, copper and selenium in whole blood and blood serum

被引:1
作者
Aydin, H
Oruc, O
机构
[1] Gazi Üniversitesi Fen-Edebiyat, Fakültesi Kimya Bölümü
来源
FRESENIUS JOURNAL OF ANALYTICAL CHEMISTRY | 1997年 / 358卷 / 7-8期
关键词
D O I
10.1007/s002160050524
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
A two-step procedure including appropriate wet-digestions, separation of selenium from interfering ions such as heavy metal ions with pentyl alcohol and anodic stripping voltammetric (ASV) determination of Pb2+, Cu2+ and SeO32- is developed. The elements in digested whole blood and serum sample solutions were determined by using a standard addition method. 1 x 10(-9) mol/L SeO32-, Cu2+ and Pb2+ were successfully determined with relative standard deviations of approximately 1-2% (n = 6-8).
引用
收藏
页码:859 / 860
页数:2
相关论文
共 16 条
[1]   A STUDY ON THE GENERATION OF HYDROGEN SELENIDE AND DECOMPOSITION OF TETRAHYDROBORATE IN HYDRIDE-GENERATION ATOMIC-ABSORPTION SPECTROMETRY [J].
AGTERDENBOS, J ;
BAX, D .
ANALYTICA CHIMICA ACTA, 1986, 188 :127-135
[2]   Semi-on-line microwave-assisted digestion of shellfish tissue for the determination of selenium by electrothermal atomic absorption spectrometry [J].
Arruda, MAZ ;
Gallego, M ;
Valcarcel, M .
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1996, 11 (02) :169-173
[3]   DIFFERENTIAL-PULSE POLAROGRAPHIC-BEHAVIOR OF SELENIUM IN THE PRESENCE OF COPPER, CADMIUM AND LEAD [J].
AYDIN, H ;
TAN, GH .
ANALYST, 1991, 116 (09) :941-945
[4]   DETERMINATION OF SELENIUM(IV) BY ANODIC-STRIPPING VOLTAMMETRY USING EXTRACTION WITH PENTYL ALCOHOL [J].
AYDIN, H ;
YAHAYA, AH .
ANALYST, 1992, 117 (01) :43-45
[5]   ANODIC-STRIPPING VOLTAMMETRY OF SELENIUM IN THE PRESENCE OF COPPER-ION [J].
AYDIN, H ;
SOMER, G .
ANALYTICAL SCIENCES, 1989, 5 (01) :89-93
[6]  
BANNON DI, 1994, CLIN CHEM, V40, P1730
[7]   Determination of lead in whole blood by capacitively coupled microwave plasma atomic emission spectrometry [J].
Besteman, AD ;
Lau, N ;
Liu, DY ;
Smith, BW ;
Winefordner, JD .
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1996, 11 (07) :479-481
[8]   Interference of copper and nickel on electrochemical hydride generation [J].
Ding, WW ;
Sturgeon, RE .
JOURNAL OF ANALYTICAL ATOMIC SPECTROMETRY, 1996, 11 (06) :421-425
[9]  
Furuta N, 1996, FRESEN J ANAL CHEM, V355, P457
[10]  
Gorsuch T. T., 1970, DESTRUCTION ORGANIC