Instrumented falling weight impact of coinjection-molded multipolypropylene sandwich plaques containing β-phase polypropylene core

被引:22
作者
Karger-Kocsis, J
Varga, J
Drummer, D
机构
[1] Univ Kaiserslautern, Inst Verbundwerkstoffe GmbH, D-67653 Kaiserslautern, Germany
[2] Tech Univ Budapest, Dept Plast & Rubber Technol, H-1521 Budapest, Hungary
[3] Univ Erlangen Nurnberg, Lehrstuhl Kunstofftech, D-91058 Erlangen, Germany
来源
JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS | 2002年 / B41卷 / 4-6期
关键词
coinjection-molding; instrumented falling weight impact; isotactic polypropylene; skin-core morphology; alpha-phase polypropylene; beta-phase polypropylene;
D O I
10.1081/MB-120013071
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The instrumented falling weight perforation impact behavior of coinjection-molded multipolypropylene sandwich plaques of various compositions having a beta-phase isotactic polypropylene (PP) homopolymer core was studied at room temperature and T = -40degreesC, respectively. The results were compared with those achieved on injection-molded monomaterial plaques of alpha- and beta-polymorphs. It was found that the coinjection strategy is beneficial only if the skin-forming alpha-phase PP has a markedly lower molecular weight than the beta-nucleated core PP. Sandwich plaques with PP copolymer skins exhibited an outstanding per-foration impact resistance. The coinjection strategy for extrusion grade PPs yielded no improvement. Perforation impact at T = -40degreesC showed a prominent toughness reduction of the multi polypropylene plaques which became comparable with that of the monolayer plaques.
引用
收藏
页码:881 / 889
页数:9
相关论文
共 13 条
[2]   Interfacial instabilities in multimaterial co-injection mouldings - Part 1 - Background and initial experiments [J].
Goodship, V ;
Kirwan, K .
PLASTICS RUBBER AND COMPOSITES, 2001, 30 (01) :11-15
[3]   Structural hierarchy developed in co-injection molded polystyrene/polypropylene parts [J].
Kadota, M ;
Cakmak, M ;
Hamada, H .
POLYMER, 1999, 40 (11) :3119-3145
[4]   Effects of molecular weight on the perforation impact behavior of injection-molded plaques of α- and β-phase isotactic polypropylenes [J].
Karger-Kocsis, J ;
Moos, E ;
Mudra, I ;
Varga, J .
JOURNAL OF MACROMOLECULAR SCIENCE-PHYSICS, 1999, B38 (5-6) :647-662
[5]   How does ''phase transformation toughening'' work in semicrystalline polymers? [J].
KargerKocsis, J .
POLYMER ENGINEERING AND SCIENCE, 1996, 36 (02) :203-210
[6]  
KargerKocsis J, 1997, J APPL POLYM SCI, V64, P2057, DOI 10.1002/(SICI)1097-4628(19970613)64:11<2057::AID-APP1>3.0.CO
[7]  
2-I
[8]   Co-injection molding:: Effect of processing on material distribution and mechanical properties of a sandwich molded plate [J].
Seldén, R .
POLYMER ENGINEERING AND SCIENCE, 2000, 40 (05) :1165-1176
[9]   An investigation on the impact fracture characteristics of EPR toughened polypropylene [J].
Tam, WY ;
Cheung, T ;
Li, RKY .
POLYMER TESTING, 1996, 15 (04) :363-380
[10]  
Varga J, 1996, J POLYM SCI POL PHYS, V34, P657, DOI 10.1002/(SICI)1099-0488(199603)34:4<657::AID-POLB6>3.0.CO