Synthesis and characterization of a vic-dioxime derivative and investigation of its complexes with Ni(II), Co(II), Cu(II) and UO2(VI)metals

被引：60

作者：

Canpolat, E ^{[1
]}

Kaya, M ^{[1
]}

机构：

[1] Univ Firat Elazig, Fac Arts & Sci, Dept Chem, Elazig, Turkey

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2002年 / 55卷 / 08期

关键词：

vic-dioxime; nickel(II); cobalt(II); copper(II); uranyl;

D O I：

10.1080/0095897022000002286

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this study, 1,2-dihdroxyimino-3,7-di-aza-9,10-O-iso-propylidene decane (LH2) was synthesized starting from 1,2-O-iso-propylidene-4-aza-7-aminoheptane (RNH2) and anti-chloroglyoxime. Complexes of this ligand with Ni(II), Co(II), Cu(II) and UO2(VI) salts were repared. Structures of the ligand and its complexes are proposed based on elemental analyses, IR, C-13 and H-1 NMR spectra magnetic susceptibility measurements and thermogravimetric analyses (TGA).

引用

页码：961 / 968

页数：8

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