Photovoltaic Property of Anatase TiO2 3-D Mesoflowers

被引:35
作者
Deepak, T. G. [1 ]
Subash, Devika [1 ]
Anjusree, G. S. [1 ]
Pai, K. R. Narendra [1 ]
Nair, Shantikumar V. [1 ]
Nair, A. Sreekumaran [1 ]
机构
[1] Amrita Vishwa Vidyapeetham, Amrita Inst Med Sci, Amrita Ctr Nanosci & Mol Med, Kochi 682041, Kerala, India
关键词
Dye-sensitized solar cell; TiO2; TiO2-SiO2; composite; Light scattering; Electrochemical impedance spectroscopy; NANOSTRUCTURES; MESOSTRUCTURES; ELECTRODES; IMPEDANCE; SPECTRA; RUTILE;
D O I
10.1021/sc500642c
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We have synthesized 3-D flower-like mesostructured TiO2 from one-dimensional electrospun TiO2-SiO2 nanocomposites through a modified titanate route for dye-sensitized solar cell (DSC) application. The TiO2 3-D mesoflowers with commendable internal surface area, crystallinity, and a good light scattering property satisfy the prerequisites of a DSC photoanode material. The starting TiO2-SiO2 composite, intermediate titanate, and final 3-D mesoflowered TiO2 were characterized by spectroscopy, microscopy, and surface area measurements. A DSC employing 3-D mesoflowered TiO2 as the photoanode showed a power conversion efficiency of 8.3% which was 23% higher than that of commercial P-25 (6.37%).
引用
收藏
页码:2772 / 2780
页数:9
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