Syntheses of four methyl-branched secondary acetates and a methyl-branched ketone as possible candidates for the female pheromone of the screwworm fly, Cochliomyia hominivorax

被引：11

作者：

Furukawa, A ^{[1
]}

Shibata, C ^{[1
]}

Mori, K ^{[1
]}

机构：

[1] Sci Univ Tokyo, Fac Sci, Dept Chem, Shinjuku Ku, Tokyo 1628601, Japan

来源：

BIOSCIENCE BIOTECHNOLOGY AND BIOCHEMISTRY | 2002年 / 66卷 / 05期

关键词：

Cochliomyia hominivorax; methyl-branched ketone; methyl-branched secondary acetate; pheromone; screwworm fly;

D O I：

10.1271/bbb.66.1164

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

6-Acetoxy-19-methylnonacosane (1), 7-acetoxy-19-methylnonacosane (2), 8-acetoxy-19-methyinonacosane (3), 7-acetoxy-15-methylnonacosane (4), and 21-methyl-7-hentriacontanone (5) were synthesized as racemic and diastereomeric mixtures. These are new compounds isolated from an HPLC fraction of the female hexane extract which elicited mating responses in the male screw-worm fly, Cochliomyia hominivorax..

引用

页码：1164 / 1169

页数：6

共 4 条

[1] IMPROVED CARBON-CARBON LINKING BY CONTROLLED COPPER CATALYSIS [J].

FOUQUET, G ;

SCHLOSSE.M .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1974, 13 (01) :82-83

[2] SYNTHESIS OF 17-BETA-ESTRADIOL DERIVATIVES WITH N-BUTYL, N-METHYL ALKYLAMIDE SIDE-CHAIN AT POSITION 15 [J].

POIRIER, D ;

MERAND, Y ;

LABRIE, F .

TETRAHEDRON, 1991, 47 (37) :7751-7766

[3] IDENTIFICATION OF COMPOUNDS IN AN HPLC FRACTION FROM FEMALE EXTRACTS THAT ELICIT MATING RESPONSES IN MALE SCREWWORM FLIES, COCHLIOMYIA-HOMINIVORAX [J].

POMONIS, JG ;

HAMMACK, L ;

HAKK, H .

JOURNAL OF CHEMICAL ECOLOGY, 1993, 19 (05) :985-1008

[4]

Shirai Y, 1999, EUR J ORG CHEM, V1999, P3139

← 1 →