Nanorods of ZnO: An effective hydrazine sensor and their chemical properties

被引:16
作者
Wahab, Rizwan [1 ]
Ahmad, Naushad [2 ]
Alam, Manawwer [2 ]
Ahmad, Javed [1 ]
机构
[1] King Saud Univ, Coll Sci, Zool Dept, POB 2455, Riyadh 11451, Saudi Arabia
[2] King Saud Univ, Coll Sci, Dept Chem, POB 2455, Riyadh 11451, Saudi Arabia
关键词
ZnONRs; Hydrazine; Amperometry; Nyquist plot; ELECTROANALYTICAL DETECTION; ELECTROCATALYTIC OXIDATION; OXIDE; FABRICATION; ELECTRODES; PERFORMANCE; BIOSENSOR; SUBSTRATE; CANCER; COBALT;
D O I
10.1016/j.vacuum.2019.04.036
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this paper, ZnO nanorods (ZnONRs) have been synthesized via chemical solution approach. The chemicals such as the nitrate salt of zinc, hexamethylenetetramine and NaOH were utilized and the acquired solution was refluxed at similar to 90 degrees C for 60 min for fabrication of nanorods. Thereafter, the obtained NRs were well characterized with the instruments such as X-ray diffraction pattern (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM) and Fourier transform infra-red (FTIR) spectroscopy also with electrochemical data. The well crystalline nanorods were used as an electrode material for to high sensitive hydrazine sensor detection with glassy carbon electrode (GCE). The cyclic voltammetry (CV) data's were analyzed from low (2 mu L/100 mL PBS) to high concentration (1-5 mL/PBS) of hydrazine with NRs/GCE electrode. The electrochemical impedance spectroscopy (EIS) was evaluated from 0 to 5 mL of solution at 4211 Z/ohm conditions. The proposed sensor and their stability are the promising features of the sensor.
引用
收藏
页码:290 / 296
页数:7
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