Effect of H2 carrier gas on the physical properties of a GaN layer grown using Ga2O vapor and NH3

被引:15
作者
Bu, Yuan [1 ]
Imade, Mamoru [1 ]
Kitamoto, Akira [1 ]
Yoshimura, Masashi [1 ]
Isemura, Masashi [2 ]
Mori, Yusuke [1 ]
机构
[1] Osaka Univ, Grad Sch Engn, Div Elect Elect & Informat Engn, Suita, Osaka 5650871, Japan
[2] Itochu Plast Inc, Shibuya Ku, Tokyo 1508525, Japan
关键词
Line defects; Impurities; Single crystal growth; Vapor phase epitaxy; Nitrides; Semiconducting III-V materials; CRYSTAL; FILMS;
D O I
10.1016/j.jcrysgro.2014.01.031
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
We investigated the effect of H-2 ratio in carrier gas on oxygen concentration, crystallinity and threading dislocation density (TDD) in GaN layers synthesized from Ga2O vapor and NH3. SIMS analysis revealed that the oxygen concentration in GaN layers decreased with increasing H-2 ratios, and achieved 8.72 x 10(17) atoms/cc with a growth rate of 50 mu m/h when the H-2 ratio was 800%. The full width at half maximum (FWHM) and TDD decreased with increasing H-2 ratios. To explain these results, we explored the growth mode at the initial growth stage in H-2 ambient, and found that the nucleation rate of the GaN crysial decreased in H-2 ambient, resulting in the improvement of crystallinity. (c) 2014 Elsevier BM. All rights reserved
引用
收藏
页码:1 / 4
页数:4
相关论文
共 18 条
[1]  
Bottcher T., 2001, APPL PHYS LETT, V78
[2]   Growth of GaN films with low oxygen concentration using Ga2O vapor and NH3 [J].
Bu, Yuan ;
Imade, Mamoru ;
Kishimoto, Hiroki ;
Yoshimura, Masashi ;
Sasaki, Takatomo ;
Kitaoka, Yasuo ;
Isemura, Masashi ;
Mori, Yusuke .
JOURNAL OF CRYSTAL GROWTH, 2011, 327 (01) :89-93
[3]   Recent achievements in AMMONO-bulk method [J].
Dwilinski, R. ;
Doradzinski, R. ;
Garczynski, J. ;
Sierzputowski, L. ;
Kucharski, R. ;
Zajac, M. ;
Rudzinski, M. ;
Kudrawiec, R. ;
Serafinczuk, J. ;
Strupinski, W. .
JOURNAL OF CRYSTAL GROWTH, 2010, 312 (18) :2499-2502
[4]   Surface Modification and Significant Reduction of Yellow/Blue Luminescence of Gallium Nitride [J].
Fang, Z. L. ;
Kang, J. Y. ;
Shen, W. Z. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (45) :17652-17656
[5]   Bulk GaN crystals grown by HVPE [J].
Fujito, Kenji ;
Kubo, Shuichi ;
Nagaoka, Hirobumi ;
Mochizuki, Tae ;
Namita, Hideo ;
Nagao, Satoru .
JOURNAL OF CRYSTAL GROWTH, 2009, 311 (10) :3011-3014
[6]   Vapor-phase epitaxial growth of GaN films using Ga2O vapor and NH3 [J].
Imade, Mamoru ;
Bu, Yuan ;
Sumi, Tomoaki ;
Kitamoto, Akira ;
Yoshimura, Masashi ;
Sasaki, Takatomo ;
Imsemura, Masashi ;
Mori, Yusuke .
JOURNAL OF CRYSTAL GROWTH, 2012, 350 (01) :56-59
[7]   Vapor-phase epitaxy of high-crystallinity GaN films using Ga2O vapor and NH3 [J].
Imade, Mamoru ;
Kishimoto, Hiroki ;
Kawamura, Fumio ;
Yoshimura, Masashi ;
Kitaoka, Yasuo ;
Sasaki, Takatomo ;
Mori, Yusuke .
JOURNAL OF CRYSTAL GROWTH, 2010, 312 (05) :676-679
[8]   Growth of a two-inch GaN single crystal substrate using the Na flux method [J].
Kawamura, Fumio ;
Umeda, Hidekazu ;
Morishita, Masanori ;
Kawahara, Minoru ;
Yoshimura, Masashi ;
Mori, Yusuke ;
Sasaki, Takatomo ;
Kitaoka, Yasuo .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 2-LETTERS & EXPRESS LETTERS, 2006, 45 (42-45) :L1136-L1138
[9]   In-situ optical monitoring of surface morphology and stoichiometry during GaN metal organic vapor phase epitaxy [J].
Kobayashi, N ;
Kobayashi, Y .
APPLIED SURFACE SCIENCE, 2000, 159 :398-404
[10]   Influence of N2 carrier gas on surface stoichiometry in GaN MOVPE studied by surface photoabsorption [J].
Kobayashi, Y ;
Kobayashi, N .
JOURNAL OF CRYSTAL GROWTH, 1998, 189 :301-304