Pyrolytic hydrolysis of polycarbonate in the presence of earth-alkali oxides and hydroxides

The rise in the use of polycarbonate (PC) calls for the development of after-use treatments. In this work, we describe a process for obtaining bisphenol A (BPA), phenol and isopropenyl phenol (IPP) from PC by hydrolysis at temperatures between 300 and 500 degrees C. The experiments were carried out in a steam atmosphere in the presence of MgO, CaO, Mg(OH)(2) or Ca(OH)(2) as catalysts, respectively. The results were compared with the hydrolysis of PC in the absence of any catalysts. All of these catalysts accelerated the hydrolysis of PC drastically, with MgO and Mg(OH)(2) being more effective than their Ca counterparts. The differences between oxides and hydroxides were negligible indicating the same mechanism for both, oxides and hydroxides. BPA was the main product at 300 degrees C, with a yield of 78% obtained in the presence of MgO. At 500 degrees C, BPA was mainly degraded to phenol and isopropenyl phenol (IPP). It can be shown that a combined process involving PC hydrolysis at 300 degrees C and BPA fission at 500 degrees C leads to high yields of phenol and IPP and the drastic decrease of residue. (C) 2009 Elsevier Ltd. All rights reserved.