On the existence of the hypervalent H3O, H2DO, HD2O, and D3O radicals

被引：6

作者：

Hvelplunda, Preben ^{[1
]}

Nielsen, Steen Brondsted ^{[1
]}

Panjaa, Subhasis ^{[1
]}

Pedersen, Jens Olaf Pepke ^{[2
]}

Uggerud, Einar ^{[3
,4
]}

机构：

[1] Aarhus Univ, Dept Phys & Astron, DK-8000 Aarhus, Denmark

[2] Tech Univ Denmark, Natl Space Inst, DK-2100 Copenhagen, Denmark

[3] Univ Oslo, Ctr Theoret & Computat Chem, N-0315 Oslo, Norway

[4] Univ Oslo, Mass Spectrometry Lab, Dept Chem, N-0315 Oslo, Norway

来源：

INTERNATIONAL JOURNAL OF MASS SPECTROMETRY | 2009年 / 281卷 / 1-2期

关键词：

Oxonium radicals; Neutral reionization; Charge reversal; Electron transfer; Kinetic isotope effect; ELECTRON-TEMPERATURE DEPENDENCE; ION-BEAM TECHNIQUES; DISSOCIATIVE RECOMBINATION; H3O&.(H2O)N-SERIES IONS; BRANCHING RATIOS; CAPTURE; NH4;

D O I：

10.1016/j.ijms.2008.12.004

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The existence of oxonium radicals on the microsecond time scale has been up for much debate, and strong isotope effects have been reported. Here we show that H3O, H2DO, HD2O, and D3O all have subnanosecond lifetimes when they are formed in charge-transfer collisions between oxonium cations and cesium. A kinetic isotope effect on hydrogen versus deuterium loss from HD2O was found to be 2.4, similar to that found in dissociative recombination of HD2O+ and for dissociation after electron transfer to HD2O+ from potassium. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：52 / 54

页数：3

共 50 条

[1] Rate constants of atomic hydrogen formation in H3O+(H2O) n + e → H + (H2O) n gas-phase processes
Stepanov, N. F.
Novakovskaya, Yu. V.
RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2009, 83 (09) : 1502 - 1510
[2] Deuterium exchange in the systems of H2O+/H2O and H3O+/H2O
Anicich, VG
Sen, AD
INTERNATIONAL JOURNAL OF MASS SPECTROMETRY, 1998, 172 (1-2) : 1 - 14
[3] Partial photoionization cross sections of NH4 and H3O Rydberg radicals
Velasco, A. M.
Lavin, C.
Martin, I.
Melin, J.
Ortiz, J. V.
JOURNAL OF CHEMICAL PHYSICS, 2009, 131 (02)
[4] Branching Ratio for O + H3+ Forming OH+ + H2 and H2O+ + H
Hillenbrand, Pierre-Michel
de Ruette, Nathalie
Urbain, Xavier
Savin, Daniel W.
ASTROPHYSICAL JOURNAL, 2022, 927 (01)
[5] An accurate 5D potential energy surface for H3O+-H2 interaction
Demes, S.
Lique, F.
Faure, A.
Rist, C.
JOURNAL OF CHEMICAL PHYSICS, 2020, 153 (09)
[6] Influence of CO2 on the Solubility of Potassium Glycinate in Glycine-KOH-H2O, Glycine-KHCO3-H2O, and Glycine-KOH-KHCO3-H2O
Rasmussen, Valdemar E.
Neerup, Randi
Stampino, Irene G.
Vinjarapu, Sai H. B.
Villadsen, Sebastian N. B.
Thomsen, Kaj
Fosbol, Philip L.
JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2022, 67 (11) : 3482 - 3493
[7] Production of vibrationally excited H2O from charge exchange of H3O+ with cesium
Mann, Jennifer E.
Xie, Zhen
Savee, John D.
Bowman, Joel M.
Continetti, Robert E.
JOURNAL OF CHEMICAL PHYSICS, 2009, 130 (04)
[8] Crystal structure and heat capacity of the mixed-valence trinuclear iron monoiodoacetate complex, [Fe(III)2Fe(II)O(O2CCH2I)6(H2O)3][Fe(III)3O(O2CCH2I)6(H2O)3]I
Nakamoto, T
Wang, Q
Miyazaki, Y
Sorai, M
POLYHEDRON, 2002, 21 (12-13) : 1299 - 1304
[9] Density, Viscosity, and Excess Properties of MDEA + H2O, DMEA + H2O, and DEEA + H2O Mixtures
Karunarathne, Sumudu S.
Eimer, Dag A.
Oi, Lars E.
APPLIED SCIENCES-BASEL, 2020, 10 (09):
[10] Ethanol amine loss in the EA-H2O-air and EA H2O-O2 systems
Moreno Alcantara, Jaime
Chavez Torres, Rosa Hilda
Colin Cruz, Arturo
Pavon Silva, Thelma Beatriz
REVISTA INTERNACIONAL DE CONTAMINACION AMBIENTAL, 2015, 31 (03): : 271 - 278

← 1 2 3 4 5 →