Multiscale tomographic analysis of polymer-nanoparticle hybrid materials for solar cells

The present work focuses on the study of the three-dimensional (3D) morphology of polymer and nanoparticle hybrid nanocomposites used as active layers in solution-processed solar cells. The hybrid consists of blends of regioregular poly(3-alkylthiophene) and CdSe nanorods. Electron tomography (ET) analysis performed in high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM) allows resolving single nanorods in the hybrid blend. These results are compared with those obtained using focused ion beam coupled with scanning electron microscopy (FIB-SEM), operated in a so-called 3D "slice-and-view" mode. This technique allows 3D information to be obtained on a whole device stack (hybrid active layers plus electrodes and the substrate) for significantly larger surface areas than with ET (similar to 10 vs. similar to 0.1 mu m(2)). The combination of ET and 3D FIB "slice-and-view" reconstructions provides complementary and coherent information on the 3D morphology of the hybrid systems at different length scales. Phase separation between the nanoparticles and the polymer is investigated by a quantitative analysis of the reconstructed volumes and is related to the performances of the hybrid devices.