High-resolution study of the three lowest infrared bands of PHD2

被引：7

作者：

Ulenikov, ON ^{[1
]}

Bekhtereva, ES

Petrunina, OL

Bürger, H

Jerzembeck, W

机构：

[1] Tomsk VV Kuibyshev State Univ, Dept Phys, Lab Mol Spect, Tomsk 634050, Russia

[2] Inst Atmospher Opt, SB RAN, Tomsk 634055, Russia

[3] Univ Gesamthsch Wuppertal, D-42097 Wuppertal, Germany

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 2002年 / 214卷 / 01期

关键词：

D O I：

10.1006/jmsp.2002.8563

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The high-resolution (2.3 x 10(-3) cm(-1)) Fourier transform infrared spectrum of PHD2 was recorded for the first time and analyzed in the region of the three lowest bands belonging to the three bending fundamentals. Between 1100 and 1800 transitions were assigned to each of the nu(3), nu(4), and nu(6) bands and 1267 upper energies were obtained thereof. These were fitted by 58 parameters, which reproduce the experimental upper energies with rms deviations of 1.3 x 10(-4) cm(-1) and 2.7x 10(-4) cm(-1) for the J less than or equal to 17 and J greater than or equal to 18 levels, respectively. (C) 2002 Elsevier Science (USA).

引用

页码：1 / 10

页数：10

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