Wireless Coupling of Conducting Polymer Actuators with Light Emission

被引:21
作者
Gupta, Bhavana [1 ]
Afonso, Mariana C. [1 ]
Zhang, Lin [1 ]
Ayela, Cedric [2 ]
Garrigue, Patrick [1 ]
Goudeau, Bertrand [1 ]
Kuhn, Alexander [1 ]
机构
[1] Univ Bordeaux, Bordeaux INP, CNRS, ISM,ENSCBP,UMR 5255, 16 Ave Pey, F-33607 Pessac, France
[2] Univ Bordeaux, Bordeaux INP, CNRS, IMS ENSCBP,UMR 5218, F-33405 Talence, France
基金
欧洲研究理事会;
关键词
bipolar electrochemistry; conducting polymers; smart materials; wireless actuation; wireless light emission; BIPOLAR ELECTROCHEMISTRY; SMART MATERIALS; JANUS OBJECTS; ELECTRODES;
D O I
10.1002/cphc.201900116
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Combining the actuation of conducting polymers with additional functionalities is an interesting fundamental scientific challenge and increases their application potential. Herein we demonstrate the possibility of direct integration of a miniaturized light emitting diode (LED) in a polypyrrole (PPy) matrix in order to achieve simultaneous wireless actuation and light emission. A light emitting diode is used as a part of an electroactive surface on which electrochemical polymerization allows direct incorporation of the electronic device into the polymer. The resulting free-standing polymer/LED hybrid can be addressed by bipolar electrochemistry to trigger simultaneously oxidation and reduction reactions at its opposite extremities, leading to a controlled deformation and an electron flow through the integrated LED. Such a dual response in the form of actuation and light emission opens up interesting perspectives in the field of microrobotics.
引用
收藏
页码:941 / 945
页数:5
相关论文
共 47 条
  • [41] On the absence of a diffuse double layer at electronically conductive polymer film electrodes. Direct evidence by atomic force microscopy of complete charge compensation
    Wang, J
    Bard, AJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (03) : 498 - 499
  • [42] Wang J., 2013, Nanomachines: Fundamentals and Applications
  • [43] Ultrathin Shape Change Smart Materials
    Xu, Weinan
    Kwok, Kam Sang
    Gracias, David H.
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2018, 51 (02) : 436 - 444
  • [44] Smart nanomaterials
    Yoshida, Mutsumi
    Lahann, Joerg
    [J]. ACS NANO, 2008, 2 (06) : 1101 - 1107
  • [45] Stimuli-Responsive Chemomechanical Actuation: A Hybrid Materials Approach
    Zarzar, Lauren D.
    Aizenberg, Joanna
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 2014, 47 (02) : 530 - 539
  • [46] Wireless Electromechanical Readout of Chemical Information
    Zhang, Lin
    Gupta, Bhavana
    Goudeau, Bertrand
    Mano, Nicolas
    Kuhn, Alexander
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2018, 140 (45) : 15501 - 15506
  • [47] Bipolar Electrodes with 100% Current Efficiency for Sensors
    Zhang, Xiaowei
    Zhai, Qingfeng
    Xing, Huanhuan
    Li, Jing
    Wang, Erkang
    [J]. ACS SENSORS, 2017, 2 (03): : 320 - 326