Amphiphilic Triblock Copolymers Based on Acrylic Acid and Alkyl Acrylates Synthesized via RAFT Polymerization-Induced Self-Assembly and RAFT Miniemulsion Polymerizations

被引：7

作者：

Serkhacheva, Natalia ^{[1
]}

Plutalova, Anna ^{[2
]}

Kozhunova, Elena ^{[3
]}

Prokopov, Nikolay ^{[1
]}

Chernikova, Elena ^{[2
]}

机构：

[1] Moscow Technol Univ, Lomonosov Inst Fine Chem Technol, Moscow 119571, Russia

[2] Moscow MV Lomonosov State Univ, Fac Chem, Moscow 119991, Russia

[3] Moscow MV Lomonosov State Univ, Fac Phys, Moscow 119991, Russia

来源：

POLYMER SCIENCE SERIES B | 2018年 / 60卷 / 02期

基金：

俄罗斯基础研究基金会; 俄罗斯科学基金会;

关键词：

AQUEOUS DISPERSION POLYMERIZATION; N-BUTYL ACRYLATE; CONTROLLED/LIVING RADICAL POLYMERIZATION; CHAIN-TRANSFER POLYMERIZATION; BENZYL METHACRYLATE; EMULSION POLYMERIZATION; MEDIATED POLYMERIZATION; BLOCK-COPOLYMER; NANO-OBJECTS; SYSTEMS;

D O I：

10.1134/S1560090418020070

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The aim of this research is to reveal the advantages and limitations of different heterophase polymerization methods, such as dispersion, emulsifier-free emulsion and miniemulsion polymerization, for the obtaining of in situ self-assembled amphiphilic triblock copolymer core-shell particles. In the present research, we addressed the problems of the controlled synthesis of two- and three-component amphiphilic ABA triblock copolymers based on acrylic acid, fluoroalkyl acrylates and butyl acrylate via polymerization induced self-assembly and reversible addition fragmentation chain transfer polymerization (RAFT) miniemulsion polymerization using symmetrical trithiocarbonates.

引用

页码：204 / 217

页数：14

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