Synthesis, Crystal Structure and Luminescent Properties of One New. Ag(I) Complex Based on 3-Aminopyrazine-2-carboxylic Acid

被引：0
作者：
Lei Xiao-Wu [1 ]
Yue Cheng-Yang [1 ]
Zhang Hui-Ping [1 ]
Zhai Xiu-Rong [1 ]
Feng Li-Juan [1 ]
机构：
[1] Jining Univ, Key Lab Inorgan Chem Univ Shandong, Dept Chem & Chem Engn, Qufu 273155, Shandong, Peoples R China
来源：
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2014年 / 33卷 / 04期
基金：
中国国家自然科学基金; 中国博士后科学基金;
关键词：
Hapca; Ag-I; crystal structure; luminescence; LIGAND;
D O I：
暂无
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
One new Ag-I complex, [Ag(apca)(H2O)](n) (Hapca = 3-aminopyrazine-2-carboxylic acid), has been prepared and structurally and spectroscopically characterized. The title complex (1) crystallizes in the monoclinic system P2(1)/c (No. 14) with a = 14.3307(9), b = 14.9296(9), c = 6.5824(4) angstrom, beta = 92.7430(10)degrees, V = 1406.70(15) angstrom(3), Z = 8. M-r = 264.00, D-c = 2.493 g/cm(3), mu = 2.831 mm(-1), F(000) = 1024, the final R = 0.0266 and wR = 0.0788 for 3107 observed reflections with I>2 sigma(I). Its structure features a three-dimensional (3D) network composed of one-dimensional (1D) [Ag(apca)(H2O)](n) ribbons interconnected via weak hydrogen bonds and pi-pi interactions. Emission spectra of the title complex in the solid state at room temperature give strong green luminescence.
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收藏
页码：635 / 641
页数：7
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