A Facile Hydrothermal Method to Synthesize Nanosized Co3O4/CeO2 and Study of its Catalytic Characteristic in Catalytic Ozonation of Phenol

被引:6
作者
He, Kun [2 ]
Dong, Yuming [3 ]
Yin, Lin [1 ]
Zhang, Aimin [4 ]
Li, Zhen [1 ]
机构
[1] Nanjing Univ, Dept Earth Sci, Nanjing 210093, Peoples R China
[2] Res Inst Petr Explorat & Dev, Beijing 100083, Peoples R China
[3] Jiangnan Univ, Sch Chem & Mat Engn, Wuxi 214122, Peoples R China
[4] Nanjing Univ, Key Lab Mesoscop Chem, Sch Chem & Chem Engn, Nanjing 210093, Peoples R China
基金
中国国家自然科学基金;
关键词
Nanosized Co3O4/CeO2; Catalytic ozonation; Phenol; COD; ACTIVATED CARBON; WATER-TREATMENT; OXALIC-ACID; OXIDATION; OZONE; DEGRADATION; DECOMPOSITION; NITROBENZENE; ALUMINA; PHASE;
D O I
10.1007/s10562-009-0105-x
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this paper nanosized Co3O4/CeO2 was successfully synthesized by a simple hydrothermal method and was applied as catalyst in catalytic ozonation of phenol in solution. The observed results show that nanoparticles have a pleasant special surface. Ozonation experiments indicate that the nanoparticles present a certain catalytic effect on the degradation of phenol and a remarkable acceleration on the chemical oxygen demand removal. Further investigations reveal that a mechanism of solid-liquid interface reactions exists in this system.
引用
收藏
页码:209 / 213
页数:5
相关论文
共 23 条
[1]   Advanced oxidation processes (AOP) for water purification and recovery [J].
Andreozzi, R ;
Caprio, V ;
Insola, A ;
Marotta, R .
CATALYSIS TODAY, 1999, 53 (01) :51-59
[2]   The use of manganese dioxide as a heterogeneous catalyst for oxalic acid ozonation in aqueous solution [J].
Andreozzi, R ;
Insola, A ;
Caprio, V ;
Marotta, R ;
Tufano, V .
APPLIED CATALYSIS A-GENERAL, 1996, 138 (01) :75-81
[3]   Gallic acid water ozonation using activated carbon [J].
Beltrán, FJ ;
García-Araya, JF ;
Giráldez, I .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2006, 63 (3-4) :249-259
[4]   A TiO2/Al2O3 catalyst to improve the ozonation of oxalic acid in water [J].
Beltrán, FJ ;
Rivas, FJ ;
Montero-de-Espinosa, R .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2004, 47 (02) :101-109
[5]   Catalytic ozonation of PCE by clay from tidal flat sediments [J].
Chung, HH ;
Jung, JH ;
Yoon, JH ;
Lee, MJ .
CATALYSIS LETTERS, 2002, 78 (1-4) :77-79
[6]   An investigation of catalytic ozonation for the oxidation of halocarbons in drinking water preparation [J].
Cooper, C ;
Burch, R .
WATER RESEARCH, 1999, 33 (18) :3695-3700
[7]   Catalytic degradation of nitrobenzene and aniline in presence of ozone by magnesia from natural mineral [J].
Dong, Yuming ;
He, Kun ;
Yin, Lin ;
Zhang, Aimin .
CATALYSIS LETTERS, 2007, 119 (3-4) :222-227
[8]   Catalytic oxidation of benzene with ozone over alumina-supported manganese oxides [J].
Einaga, H ;
Futamura, S .
JOURNAL OF CATALYSIS, 2004, 227 (02) :304-312
[9]   A nanometer-ZnO catalyst to enhance the ozonation of 2,4,6-trichlorophenol in water [J].
Huang, WJ ;
Fang, GC ;
Wang, CC .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2005, 260 (1-3) :45-51
[10]   Catalytic decomposition of ozone and para-Chlorobenzoic acid (pCBA) in the presence of nanosized ZnO [J].
Jung, Haeryong ;
Choi, Heechul .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2006, 66 (3-4) :288-294