Catalytic activity of hierarchical beta zeolites in the Prins cyclization of (-)-isopulegol with acetone

被引：14
|
作者：
Laluc, Mathias [1 ]
Barakov, Roman [2 ,3 ]
Maki-Arvela, Paivi [1 ]
Shcherban, Nataliya [2 ]
Murzin, Dmitry Yu [1 ]
机构：
[1] Abo Akad Univ, Fac Sci & Engn, Johan Gadolin Proc Chem Ctr, Turku 20500, Finland
[2] Natl Acad Sci Ukraine, LV Pisarzhevsky Inst Phys Chem, 31 Pr Nauky, UA-03028 Kiev, Ukraine
[3] Charles Univ Prague, Fac Sci, Dept Phys & Macromol Chem, Hlavova 2030, Prague 12840 2, Czech Republic
来源：
APPLIED CATALYSIS A-GENERAL | 2021年 / 618卷
基金：
新加坡国家研究基金会;
关键词：
Hierarchical zeolite; Prins cyclisation; Chromenol; Tetrahydropyran ring structure; ACIDITY; OCTAHYDRO-2H-CHROMEN-4-OL; STRATEGIES; ISOPULEGOL; ADSORPTION; VANILLIN;
D O I：
10.1016/j.apcata.2021.118131
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Several hierarchical beta zeolites prepared via hydrothermal treatment of a concentrated zeolite gel-precursor were investigated in Prins cyclisation between (-)-isopulegol and acetone acting as a reactant and a solvent for production of a chromenol compound exhibiting antiviral activity. The catalysts were characterized by SEM, TEM, nitrogen physisorption, ammonia TPD, adsorption-desorption of pyridine and 2,4,6-tri-tert-butylpyridine with FTIR spectroscopy. For the Prins cyclization performed at 30 degrees C, the highest yield of the desired product was obtained over a zeolite catalyst containing a developed mesoporosity with a uniform mesopore size and an optimum ratio of Bronsted to Lewis acid sites.
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页数：10
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