Photocatalytic activity and adsorption performance of p-CuBi2O4/n-TiO2 p-n heterojunction composites prepared by in situ sol-gel coating method

被引:23
作者
Zhang, Yun [1 ]
Xie, Yahong [1 ,2 ]
Li, Juan [1 ]
Bai, Te [1 ]
Wang, Jide [1 ]
机构
[1] Xinjiang Univ, Key Lab Oil & Gas Fine Chem, Minist Educ & Xinjiang Uyghur Autonomous Reg, Urumqi 830046, Peoples R China
[2] Chinese Acad Sci, Xinjiang Tech Inst Phys & Chem, Urumqi 830046, Peoples R China
关键词
CuBi2O4; TiO2; p-n heterojunction; Photocatalytic; Adsorption performance; AQUEOUS-SOLUTION; LIGHT; DEGRADATION; OXIDATION;
D O I
10.1007/s10971-014-3328-2
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The CuBi2O4/TiO2 p-n heterojunction composites were obtained by in situ sol-gel coating process using prepared CuBi2O4 powders and titania colloid. The obtained CuBi2O4/TiO2 composites were characterized by XRD, SEM, BET and UV-vis diffuse reflectance spectroscopy. Their photocatalytic and adsorption activities were evaluated by degradations and adsorptions of methyl orange and congo red. Results showed that some compositions of prepared p-n heterojunction composites exhibited much higher photocatalytic activity and absorption performance than pure CuBi2O4 or pure TiO2, demonstrating that the formation of p-n heterojunction between the two materials plays an important role in improving photocatalytic activity and adsorption performance.
引用
收藏
页码:38 / 42
页数:5
相关论文
共 22 条
[1]   Synthesis, characterization and UV-A light photocatalytic activity of 20 wt%SrO-CuBi2O4 composite [J].
Abdelkader, Elaziouti ;
Nadjia, Laouedj ;
Ahmed, Bekka .
APPLIED SURFACE SCIENCE, 2012, 258 (12) :5010-5024
[2]   CuBi2O4 single crystal nanorods prepared by hydrothermal method: Growth mechanism and optical properties [J].
Abdulkarem, A. M. ;
Li, Jialin ;
Aref, A. A. ;
Ren, Lu ;
Elssfah, E. M. ;
Wang, Hui ;
Ge, Yunke ;
Yu, Ying .
MATERIALS RESEARCH BULLETIN, 2011, 46 (09) :1443-1450
[3]  
Ahmad Ali P, 2005, IRAN J CHEM CHEM ENG, V24, P41
[4]   Sonochemical synthesis of Bi2CuO4 nanoparticles for catalytic degradation of nonylphenol ethoxylate [J].
Anandan, Sambandam ;
Lee, Gang-Juan ;
Yang, Chuan-Kai ;
Ashokkumar, Muthupandian ;
Wu, Jerry J. .
CHEMICAL ENGINEERING JOURNAL, 2012, 183 :46-52
[5]   Efficient complete oxidation of acetaldehyde into CO2 over CuBi2O4/WO3 composite photocatalyst under visible and UV light irradiation [J].
Arai, Takeo ;
Yanagida, Masatoshi ;
Konishi, Yoshinari ;
Iwasaki, Yasukazu ;
Sugihara, Hideki ;
Sayama, Kazuhiro .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (21) :7574-7577
[6]   Preparation and activity evaluation of relative p-n junction photocatalyst Co-TiO2/TiO2 [J].
Chen Shifu ;
Liu Wei ;
Zhang Sujuan ;
Chen Yinghao .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2010, 54 (02) :258-267
[7]   Hierarchical Bi2CuO4 microspheres: Hydrothermal synthesis and catalytic performance in wet oxidation of methylene blue [J].
Chen, Xiang Ying ;
Ma, Chao ;
Li, Xiao Xuan ;
Chen, Peng ;
Fang, Ji Guo .
CATALYSIS COMMUNICATIONS, 2009, 10 (06) :1020-1024
[8]   The electronic origin of the visible-light absorption properties of C-, N- and S-doped TiO2 nanomaterials [J].
Chen, Xiaobo ;
Burda, Clemens .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (15) :5018-+
[9]   Visible-Solar-Light-Driven Photocatalytic Degradation of Phenol with Dye-Sensitized TiO2: Parametric and Kinetic Study [J].
Chowdhury, Pankaj ;
Moreira, Jesus ;
Gomaa, Hassan ;
Ray, Ajay K. .
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (12) :4523-4532
[10]   Preparation, characterization and photocatalytic activity of CuBi2O4/NaTaO3 coupled photocatalysts [J].
Deng, Yongyong ;
Chen, Youjian ;
Chen, Bingang ;
Ma, Jianhua .
JOURNAL OF ALLOYS AND COMPOUNDS, 2013, 559 :116-122