Ni Catalyst Coating on Fecralloy® Microchanneled Foils and Testing for Methane Steam Reforming

被引:11
作者
de Miguel, Nerea [1 ]
Manzanedo, Jaio [1 ]
Thormann, Janina [2 ]
Pfeifer, Peter [2 ]
Luis Arias, Pedro [3 ]
机构
[1] Ikerlan S Coop, Alternat Generat Syst, Minano 01510, Alava, Spain
[2] Karlsruhe Inst Technol, Inst Micro Proc Engn, Karlsruhe, Germany
[3] Univ Basque Country, Bilbao, Spain
关键词
Methane steam reforming; Microchanneled foils; Microreactor; Ni catalyst system; HYDROGEN GENERATION; SYNTHESIS GAS; WASHCOATS; REACTOR; NI/AL2O3; NI/MGO; CERIA;
D O I
10.1002/ceat.200900439
中图分类号
TQ [化学工业];
学科分类号
0817 ;
摘要
The procedure following the washcoating of three different Ni catalyst systems (MgO, Al2O3, and CeO2/Al2O3 supported) on pretreated Fecralloy (R) microchanneled foils under controlled milling times and viscosities of the slurries is described. The activity of the prepared coatings is also presented. Four different series of coated foils were prepared: one per each catalyst system, keeping constant the average particle size on 5 mu m, and one extra series to study the effect of reducing the average particle size of the MgO-supported catalyst system to 3 mu m. For each coating, scanning electron microscopy pictures were taken and specific surface areas and average densities of the catalyst layers were estimated. Finally, each series of coated foils was stacked and tested in a microreactor for the methane steam reforming (MSR) reaction under different conditions.
引用
收藏
页码:155 / 166
页数:12
相关论文
共 35 条
[1]   The effect of particle size on the adhesion properties of oxide washcoats on cordierite honeycombs [J].
Agrafiotis, C ;
Tsetsekou, A ;
Ekonomakou, A .
JOURNAL OF MATERIALS SCIENCE LETTERS, 1999, 18 (17) :1421-1424
[2]   The effect of processing parameters on the properties of γ-alumina washcoats deposited on ceramic honeycombs [J].
Agrafiotis, C ;
Tsetsekou, A .
JOURNAL OF MATERIALS SCIENCE, 2000, 35 (04) :951-960
[3]   The effect of powder characteristics on washcoat duality. Part I: Alumina washcoats [J].
Agrafiotis, C ;
Tsetsekou, A .
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 2000, 20 (07) :815-824
[4]   Wet ball milling of zeolite HY [J].
Akçay, K ;
Sirkecioglu, A ;
Tatlier, M ;
Savasçi, OT ;
Erdem-Senatalar, A .
POWDER TECHNOLOGY, 2004, 142 (2-3) :121-128
[5]   Monolithic reactors for environmental applications -: A review on preparation technologies [J].
Avila, P ;
Montes, M ;
Miró, EE .
CHEMICAL ENGINEERING JOURNAL, 2005, 109 (1-3) :11-36
[6]   Fuel cells for distributed generation in developing countries - an analysis [J].
Bauen, A ;
Hart, D ;
Chase, A .
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2003, 28 (07) :695-701
[7]   The beneficial effect of silica on the activity and thermal stability of PtCoFerrierite-washcoated cordierite monoliths for the SCR of NOx with CH4 [J].
Boix, AV ;
Zamaro, JM ;
Lombardo, EA ;
Miró, EE .
APPLIED CATALYSIS B-ENVIRONMENTAL, 2003, 46 (01) :121-132
[8]  
Cao CS, 2005, CATAL TODAY, V110, P92, DOI 10.1016/j.cattod.2005.09.004
[9]   Reforming catalysts for hydrogen generation in fuel cell applications [J].
Cheekatamarla, Praveen K. ;
Finnerty, C. M. .
JOURNAL OF POWER SOURCES, 2006, 160 (01) :490-499
[10]   The effect of CeO2 structure on the activity of supported Pd catalysts used for methane steam reforming [J].
Craciun, R ;
Daniell, W ;
Knözinger, H .
APPLIED CATALYSIS A-GENERAL, 2002, 230 (1-2) :153-168