Asymmetric Catalysis Powered by Chiral Cyclopentadienyl Ligands

被引：179

作者：

Newton, Christopher G. ^{[1
]}

Kossler, David ^{[1
]}

Cramer, Nicolai ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Chem Sci & Engn, Lab Asymmetr Catalysis & Synth, CH-1015 Lausanne, Switzerland

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2016年 / 138卷 / 12期

基金：

瑞士国家科学基金会; 欧洲研究理事会;

关键词：

C-H FUNCTIONALIZATION; (ELECTRON-DEFICIENT ETA(5)-CYCLOPENTADIENYL)RHODIUM(III) CATALYST; OXIDATIVE ANNULATION; 2+2+2 CYCLOADDITION; AMBIENT CONDITIONS; IRIDIUM COMPLEXES; BOND FORMATION; ACTIVATION; ALKENES; ALKYNES;

D O I：

10.1021/jacs.5b12964

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Application of chiral derivatives of the versatile and ubiquitous cyclopentadienyl ligand has long remained an underdeveloped area in asymmetric catalysis. In this Perspective we highlight recent exciting results that demonstrate their enormous potential. In particular, we provide a comparative analysis of the available ligand families, an overview of their complexation chemistry, and an examination of their application in catalytic enantioselective reactions. We also discuss current limitations and speculate on the developments that are necessary to advance the field further.

引用

页码：3935 / 3941

页数：7

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