Cu-Based Nanocatalysts for CO2 Hydrogenation to Methanol

被引：117

作者：

Murthy, Pradeep S. ^{[1
]}

Liang, Weibin ^{[1
]}

Jiang, Yijiao ^{[2
]}

Huang, Jun ^{[1
]}

机构：

[1] Univ Sydney, Sch Chem & Biomol Engn, Sydney Nano Inst, Sydney, NSW 2006, Australia

[2] Macquarie Univ, Dept Engn, Sydney, NSW 2109, Australia

来源：

ENERGY & FUELS | 2021年 / 35卷 / 10期

基金：

澳大利亚研究理事会;

关键词：

CARBON-DIOXIDE HYDROGENATION; HYDROTALCITE-LIKE PRECURSORS; GAS SHIFT REACTION; CONTACT QUANTIFICATION MODEL; ZNO/CU(111) CATALYSTS ROLE; METAL-ORGANIC FRAMEWORKS; BIMETALLIC CATALYSTS; HIGHER ALCOHOLS; DIMETHYL ETHER; GRAPHENE OXIDE;

D O I：

10.1021/acs.energyfuels.1c00625

中图分类号：

TE [石油、天然气工业]; TK [能源与动力工程];

学科分类号：

0807 ; 0820 ;

摘要：

Production of methanol from CO2 hydrogenation is a highly attractive method toward recycling greenhouse gases to form clean, high-value commodity chemicals and fuels, with the aim of resolving both environmental issues and energy shortages. This review provides an overview of Cu-based nanocatalyst development for CO2 hydrogenation to methanol that has been achieved recently in terms of support design, promoter addition, and structural improvements, as this line of research has become very popular. In addition, the reaction mechanisms from both experimental work and density functional theory calculations are summarized to showcase key factors influencing the reaction. The overall methanol yield can be tailored by metal active sites and metal-support interaction, as well as the function of promoters. The technical and application challenges of methanol production from CO2 hydrogenation are also summarized with proposed future research directions.

引用

页码：8558 / 8584

页数：27

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