Visible-light induced divergent dearomatization of indole derivatives: controlled access to cyclobutane-fused polycycles and 2-substituted indolines

被引：31
|
作者：
Zhuang, Weihui [1 ]
Cheng, Yuan-Zheng [2 ]
Huang, Xu-Lun [2 ]
Huang, Qiufeng [1 ]
Zhang, Xiao [1 ]
机构：
[1] Fujian Normal Univ, Coll Chem & Mat Sci, Fujian Key Lab Polymer Sci, Fujian Prov Key Lab Adv Mat Oriented Chem Engn, 8 Shangsan Lu, Fuzhou 350007, Peoples R China
[2] Univ Chinese Acad Sci, Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem,Ctr Excellence Mo, 345 Lingling Lu, Shanghai 200032, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2021年 / 8卷 / 02期
关键词：
PHOTOREDOX CATALYSIS; CASCADE REACTION; RAPID SYNTHESIS; PYRROLOINDOLINES; FUNCTIONALIZATION; PHOTOCATALYSIS; CONSTRUCTION; STRATEGIES;
D O I：
10.1039/d0qo01322f
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A photocatalytic protocol for the divergent dearomative functionalization of indole derivatives is reported. Under the irradiation of visible light, either dimerization or reduction occurs selectively by modifying the reaction conditions, leading to the formation of the corresponding cyclobutane-fused polycycles and 2-substituted indolines in good yields with exclusive selectivity.
引用
收藏
页码：319 / 325
页数：7
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