Renewable polymers from lignin via copper-free thermal click chemistry

被引：72

作者：

Han, Yanming ^{[1
,2
]}

Yuan, Liang ^{[2
]}

Li, Gaiyun ^{[1
]}

Huang, Luohua ^{[1
]}

Qin, Tefu ^{[1
]}

Chu, Fuxiang ^{[1
]}

Tang, Chuanbing ^{[2
]}

机构：

[1] Chinese Acad Forestry, Inst Wood Ind, Lab Wood Chem & Applicat, Beijing 100091, Peoples R China

[2] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA

来源：

POLYMER | 2016年 / 83卷

基金：

美国国家科学基金会;

关键词：

Lignin; Renewable polymers; Click chemistry; FUNCTIONALIZATION; CYCLOADDITIONS; COMPOSITES; COPOLYMERS; RESOURCES; ROUTE; ROSIN;

D O I：

10.1016/j.polymer.2015.12.010

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The heterogeneous and multifunctional characteristics of lignin is a paradox for its potential in polymer applications, despite its renewable and aromatic nature. We demonstrate a simple approach to the preparation of renewable lignin-grafted polymers via robust copper-free thermal click chemistry. High lignin content polymers were prepared between polymer pairs containing azide and alkyne groups with tunable compositions including PEG, PCL and PLA. (C) 2015 Elsevier Ltd. All rights reserved.

引用

页码：92 / 100

页数：9

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