A highly-sensitive "turn on" probe based on coumarin β-diketone for hydrazine detection in PBS and living cells

被引：28

作者：

Chen, Rui ^{[1
]}

Shi, Guang-Jin ^{[1
]}

Wang, Jia-Jia ^{[1
]}

Qin, Hai-Feng ^{[1
]}

Zhang, Qi ^{[1
]}

Chen, Shaojin ^{[1
]}

Wen, Yonghong ^{[1
]}

Guo, Jia-Bin ^{[1
]}

Wang, Kun-Peng ^{[1
]}

Hu, Zhi-Qiang ^{[1
]}

机构：

[1] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Key Lab Opt Elect Sensing & Analyt Chem Life Sci, MOE, Qingdao 266042, Peoples R China

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2021年 / 252卷

基金：

中国国家自然科学基金;

关键词：

Hydrazine; Coumarin; beta-diketone; Fluorescent probe; Highly-sensitive; FLUORESCENT-PROBE; SELECTIVE DETECTION; AQUEOUS-SOLUTION; OPTICAL PROBE; WATER SAMPLES; GAS STATE; CHEMOSENSOR; TOXICITY; DESIGN; SENSOR;

D O I：

10.1016/j.saa.2021.119510

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Herein, a new "turn on" fluorescent probe C-1 is developed to specifically detect hydrazine using coumarin nucleus as the fluorophore and beta-diketone as the recognition group. The probe shows high selectivity towards hydrazine over other common ions and amine-containing species, as well as good water solubility and quantitative detectability of hydrazine in concentration range of 1-200 mu M. The detection limit is as low as 1.89 ppb, which is lower than the threshold set by EPA (10 ppb). Probe-coated filter papers are confirmed to detect gaseous hydrazine successfully through obvious fluorescence color changes. In addition, the probe has been verified to detect hydrazine in actual water environment and living cells. (C) 2021 Elsevier B.V. All rights reserved.

引用

页数：9

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