[Re(CO)3Cl(C5H4ClP)2] and [Re(CO)2Cl(C5H4ClP)3]: synthesis and characterization of two novel rhenium(I) phosphinine complexes

被引：2

作者：

Hollering, Manuela ^{[1
,2
]}

Reithmeier, Richard O. ^{[1
]}

Meister, Simon ^{[1
]}

Herdtweck, Eberhardt ^{[2
]}

Kuehn, Fritz E. ^{[2
]}

Rieger, Bernhard ^{[1
]}

机构：

[1] Tech Univ Munich, WACKER Chair Macromol Chem, Lichtenberg Str 4, D-85748 Garching, Germany

[2] Tech Univ Munich, Catalysis Res Ctr, Chair Inorgan Chem Mol Catalysis, Lichtenberg Str 4, D-85748 Garching, Germany

来源：

RSC ADVANCES | 2016年 / 6卷 / 17期

关键词：

MOLECULAR-ORBITAL METHODS; COORDINATION CHEMISTRY; METAL-COMPLEXES; BASIS-SETS; REACTIVITY; LIGANDS; HETEROARENES;

D O I：

10.1039/c5ra25904e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two novel rhenium(I) phosphinine complexes [Re(CO)(3)Cl(eta(1)-C5H4ClP)(2)] (1) and [Re(CO)(2)Cl(eta(1)-C5H4ClP)(3)] (2) were synthesized and themolecular structure of both was determined by single crystal X-ray diffraction. In compound 1 the two coordinated phosphinine ligands are arranged in a cis position, whereas compound 2 with three phosphinine ligands crystallizes in a meridional structural motif. Density functional theory investigations were executed to examine the relative stabilities of both complexes 1 and 2.

引用

页码：14134 / 14139

页数：6

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