Cross-Coupling Reactions of Alkyl Halides with Aryl Grignard Reagents Using a Tetrachloroferrate with an Innocent Countercation

被引：2
|
作者：
Hashimoto, Toru [1 ]
Maruyama, Tsubasa [1 ]
Yamaguchi, Takamichi [1 ]
Matsubara, Yutaka [1 ]
Yamaguchi, Yoshitaka [1 ]
机构：
[1] Yokohama Natl Univ, Grad Sch Engn, Dept Adv Mat Chem, Hodogaya Ku, 79-5 Tokiwadai, Yokohama, Kanagawa 2408501, Japan
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2019年 / 361卷 / 18期
关键词：
Iron; ferrate salt; cross-coupling reaction; alkyl halide; Grignard reagent; CATALYZED KUMADA; ALKENYL HALIDES; COMPLEX BEARING; IRON-PHOSPHINE; ATE COMPLEX; REACTIVITY; CHLORIDES; LIGAND; NUCLEOPHILES; BENZYL;
D O I：
10.1002/adsc.201900568
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Bis(triphenylphosphoranylidene)ammonium tetrachloroferrate, (PPN)[FeCl4] (1), was evaluated as a catalyst for cross-coupling reactions. 1 exhibits high stability toward air and moisture and is an effective catalyst for the reaction of secondary alkyl halides with aryl Grignard reagents. The PPN cation is considered as an innocent counterpart to the iron center. We have developed an easy-to-handle iron catalyst for "ligand-free" cross-coupling reactions.
引用
收藏
页码：4232 / 4236
页数：5
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