Thermal Pressure Coefficient of a Polyhedral Oligomeric Silsesquioxane (POSS)-Reinforced Epoxy Resin

被引:7
|
作者
Win, K. Z. [1 ]
Karim, Taskin [1 ]
Li, Qingxiu [1 ]
Simon, Sindee L. [1 ]
McKenna, Gregory B. [1 ]
机构
[1] Texas Tech Univ, Dept Chem Engn, Lubbock, TX 79409 USA
基金
美国国家航空航天局;
关键词
nanocomposites; residual stress; thermal pressure coefficient; POSS; thermoset; epoxy; polymer; high-pressure vessel; GLASS-TRANSITION TEMPERATURE; ISOTROPIC RESIDUAL-STRESSES; TIME-DEPENDENT FAILURE; CURE; POLYMERS; SYSTEM;
D O I
10.1002/app.31502
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The thermal presssure coefficients of a neat, unfilled, epoxy resin and a 10 wt % POSS (polyhedral oligomeric silsesquioxane)-filled epoxy nanocomposite have been measured Using a thick-walled tube method. It is found that just below the glass transition temperature the thermal pressure coefficient is similar to 20%, smaller for the polymer composite containing 10% POSS than for the neat, unfilled resin. The thermal expansion coefficient and thermal pressure coefficient of the uncured POSS itself are also reported. (C) 2009 Wiley Periodicals, Inc. J Appl Polym Sci 116:142-146, 2010
引用
收藏
页码:142 / 146
页数:5
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