Preparation and characterization of Ni catalysts supported on organized mesoporous alumina

被引:4
作者
Li Cui-Ping [1 ]
Zhao Rui-Hong
Guo Fen
Chen Jian-Feng
机构
[1] Beijing Inst Chem Technol, Res Ctr, Minist Educ High Grav Engn & Technol, Beijing 100029, Peoples R China
[2] Hebei Univ Sci & Technol, Sch Chem & Pharmaceut Engn, Shijiazhuang 050018, Peoples R China
关键词
organized mesoporous alumina; supported; in-situ synthesis; impregnation; nickel;
D O I
10.3866/PKU.WHXB20070204
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Ni catalysts supported on mesoporous alumina (Ni-Al2O1) were prepared by in-situ synthesis method and traditional impregnation method. The physical, chemical, and structure properties of synthesized catalysts were investigated by several measuring technologies (BET, TEM, XRD, TG). The experimental results showed that Ni-Al2O1 with high surface area (> 210 m(2) (.) g(-1)) and narrow pore size distribution (4 nm) could be synthesized by both in-situ synthesis method and impregnation method. In contrast to the impregnation method, the interaction between nickel ion and the carrier was stronger in Ni-Al2O3 synthesized by in-situ synthesis method, and the structure of pore showed to be organized in some degree.
引用
收藏
页码:157 / 161
页数:5
相关论文
共 16 条
  • [1] Catalytic autothermal reforming of methane and propane over supported metal catalysts
    Ayabe, S
    Omoto, H
    Utaka, T
    Kikuchi, R
    Sasaki, K
    Teraoka, Y
    Eguchi, K
    [J]. APPLIED CATALYSIS A-GENERAL, 2003, 241 (1-2) : 261 - 269
  • [2] CATALYTIC CONVERSION OF CCL2F2 ON A GAMMA-AL2O3 CATALYST
    BELL, TN
    KIRSZENSZTEJN, P
    CZAJKA, B
    [J]. CATALYSIS LETTERS, 1995, 30 (1-4) : 305 - 312
  • [3] HUANG H, 2005, IND CATALYSIS, V13, P13
  • [4] High activity of highly loaded MoS2 hydrodesulfurization catalysts supported on organised mesoporous alumina
    Kaluza, L
    Zdrazil, M
    Zilková, N
    Cejka, J
    [J]. CATALYSIS COMMUNICATIONS, 2002, 3 (04) : 151 - 157
  • [5] Synthesis and characterization of mesoporous alumina with nickel incorporated for use in the partial oxidation of methane into synthesis gas
    Kim, P
    Kim, Y
    Kim, H
    Song, IK
    Yi, J
    [J]. APPLIED CATALYSIS A-GENERAL, 2004, 272 (1-2) : 157 - 166
  • [6] Synthesis and characterization of mesoporous alumina for use as a catalyst support in the hydrodechlorination of 1,2-dichloropropane: effect of preparation condition of mesoporous alumina
    Kim, P
    Kim, Y
    Kim, H
    Song, IK
    Yi, J
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 219 (01) : 87 - 95
  • [7] Synthesis of mesoporous γ-alumina through pre- and post-hydrolysis methods
    Kim, Y
    Lee, B
    Yi, J
    [J]. KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2002, 19 (05) : 908 - 910
  • [8] ORDERED MESOPOROUS MOLECULAR-SIEVES SYNTHESIZED BY A LIQUID-CRYSTAL TEMPLATE MECHANISM
    KRESGE, CT
    LEONOWICZ, ME
    ROTH, WJ
    VARTULI, JC
    BECK, JS
    [J]. NATURE, 1992, 359 (6397) : 710 - 712
  • [9] Kinetics and stereoselectivity of o-xylene hydrogenation over Pd/Al2O3
    Neyestanaki, AK
    Mäki-Arvela, P
    Backman, H
    Karhu, H
    Salmi, T
    Väyrynen, J
    Murzin, DY
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2003, 193 (1-2) : 237 - 250
  • [10] Park Y, 2003, STUD SURF SCI CATAL, V146, P637