Anionic Polymerization of Methacrylate-functionalized Ionic Monomers in Ionic Liquid

被引：3

作者：

Otozawa, Nobuyuki ^{[1
,2
]}

Yoshioka, Masataka ^{[3
,4
]}

Ihara, Daiki ^{[1
]}

Hamajima, Rio ^{[3
,4
]}

Kato, Raito ^{[3
,4
]}

Terao, Toshiki ^{[3
,4
]}

Fukuma, Hiroto ^{[3
,4
]}

Kuretani, Satoshi ^{[3
,4
]}

Seko, Tamio ^{[3
,4
]}

Fujii, Syuji ^{[3
,4
]}

Nakamura, Yoshinobu ^{[3
,4
]}

Kobayashi, Motoyasu ^{[5
]}

Takahara, Atsushi ^{[1
]}

Hirai, Tomoyasu ^{[3
,4
]}

机构：

[1] Kyushu Univ, Inst Mat Chem & Engn, Nishi Ku, 744 Motooka, Fukuoka 8190395, Japan

[2] AGC Inc, Kanagawa Ku, 1150 Hazawa Cho, Yokohama, Kanagawa 2218755, Japan

[3] Osaka Inst Technol, Fac Engn, Dept Appl Chem, Asahi Ku, 5-16-1 Omiya, Osaka 5358585, Japan

[4] Osaka Inst Technol, Grad Sch Engn, Asahi Ku, 5-16-1 Omiya, Osaka 5358585, Japan

[5] Kogakuin Univ, Sch Adv Engn, Dept Appl Chem, 2665-1 Nakano Machi, Hachioji, Tokyo 1920015, Japan

来源：

CHEMISTRY LETTERS | 2020年 / 49卷 / 12期

关键词：

Anionic polymerization; Stereoregularity; Ionic liquid; POLYMERS; BRUSHES; COMPLEX; PMMA;

D O I：

10.1246/cl.200546

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Anionic polymerization of methacrylate-functionalized ionic monomers, 2-(methacryloyloxy)ethyltrimethylammonium chloride (MTAC) and 3-(N-2-methacryloyloxyethyl-N,N-dimethyl)-ammonatopropanesulfonate (MAPS), was performed using conventional alkyl lithium as an initiator in ionic liquid, leading to poly(MTAC) (PMTAC) and poly(MAPS) (PMAPS). During an anionic polymerization, ionic liquid acts as solvent and additive. The dual role of ionic liquid gives PMAPS heterotactic configuration.

引用

页码：1459 / 1461

页数：3

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