A novel probe for selective colorimetric sensing of Fe(II) and Fe(III) and specific fluorometric sensing of Fe(III): DFT calculation and logic gate application

被引:21
作者
Ghosh, Kaushik [1 ]
Rathi, Sweety [1 ]
机构
[1] Indian Inst Technol, Dept Chem, Roorkee 247667, Uttar Pradesh, India
关键词
MOLECULAR KEYPAD LOCK; RHODAMINE-BASED FLUORESCENT; CHEMOSENSOR; IONS; FE3+; SENSOR; IRON(III); HG2+; RECOGNITION; CATIONS;
D O I
10.1039/c4ra07731h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel fluorescent probe 1(2-((2-(naphthalen-1-ylamino)ethylimino)methyl)phenol) has been synthesized and characterized by various spectroscopic methods. Probe 1 was found to be highly selective for iron over tested metal ions. The naked eye detection of iron is useful for the discrimination of the +2 and +3 oxidation state while fluorescence studies conclude selective and specific sensitivity towards Fe(III).
引用
收藏
页码:48516 / 48521
页数:6
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