Water Remediation by Adsorption of Phenol onto Hydrophobic Modified Clay

被引:45
作者
Froehner, Sandro [1 ]
Martins, Raquel Fernandes [1 ]
Furukawa, Willian [1 ]
Errera, Marcelo Risso [1 ]
机构
[1] Univ Fed Parana, Dept Engn Ambiental, Ctr Polytecn, BR-81531990 Curitiba, Parana, Brazil
关键词
Remediation; Pollutants removal; Organoclays; Water pollution; Xenobiotics; AQUEOUS-SOLUTIONS; ADSORBENT; REMOVAL;
D O I
10.1007/s11270-008-9863-0
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
In this work we studied the phenol sorption from contaminated water onto modified clay mineral vermiculite and bentonite by insertion of hexadecyltrimethylammonium in the interlayer of clays. The non modified clays showed negligible interaction with phenol. The experimental data were treated using the Freunlich equation which had a good fit. The removal percentages were higher than 35% for modified vermiculite and for modified bentonite, 30%. Vermiculite and bentonite were compared for the removal of phenol from an aqueous solution based on the maximum adsorption capacity of each adsorbent, and no significant difference was found. The adsorption mechanism for both is the same, according to the results. Although, there is a lack of studies using vermiculite for this purpose, it can be concluded that hydrophobic modified vermiculite is very effective for removing phenol from water. Hydrophobic modified bentonite also remove phenol, but in lower proportions.
引用
收藏
页码:107 / 113
页数:7
相关论文
共 24 条
[11]  
Hesse P.R., 1971, TXB SOIL CHEM ANAL
[12]   Mechanism of sorption of phenols from aqueous solutions onto surfactant-modified montmorillonite [J].
Juang, RS ;
Lin, SH ;
Tsao, KH .
JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2002, 254 (02) :234-241
[13]   Adsorption of dodecyl- and octadecyltrimethylammonium ions on a smectite and synthetic micas [J].
Klapyta, Z ;
Fujita, T ;
Iyi, N .
APPLIED CLAY SCIENCE, 2001, 19 (1-6) :5-10
[14]   Surfactant-modified clay as adsorbent for chromate [J].
Krishna, BS ;
Murty, DSR ;
Prakash, BSJ .
APPLIED CLAY SCIENCE, 2001, 20 (1-2) :65-71
[15]   Adsorption of phenol and chlorinated phenols from aqueous solution by tetramethylammonium- and tetramethylphosphonium-exchanged montmorillonite [J].
Lawrence, MAM ;
Kukkadapu, RK ;
Boyd, SA .
APPLIED CLAY SCIENCE, 1998, 13 (01) :13-20
[16]   Effect of soil texture on surfactant-based remediation of hydrophobic organic-contaminated soil [J].
Lee, DH ;
Cody, RD ;
Kim, DJ ;
Choi, S .
ENVIRONMENT INTERNATIONAL, 2002, 27 (08) :681-688
[17]   SHAPE-SELECTIVE ADSORPTION OF AROMATIC-MOLECULES FROM WATER BY TETRAMETHYLAMMONIUM SMECTITE [J].
LEE, JF ;
MORTLAND, MM ;
BOYD, SA ;
CHIOU, CT .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1989, 85 :2953-2962
[18]  
NIR S, 2007, APPL CLAY SCI, V36, P174, DOI DOI 10.1016/J.CLAY.2006.04.012
[19]   Water remediation by micelle-clay system: Case study for tetracycline and sulfonamide antibiotics [J].
Polubesova, Tamara ;
Zadaka, Dikla ;
Groisman, Ludmila ;
Nir, Shlomo .
WATER RESEARCH, 2006, 40 (12) :2369-2374
[20]   BTEX removal from produced water using surfactant-modified zeolite [J].
Ranck, JM ;
Bowman, RS ;
Weeber, JL ;
Katz, LE ;
Sullivan, EJ .
JOURNAL OF ENVIRONMENTAL ENGINEERING-ASCE, 2005, 131 (03) :434-442