Reactions of 3-amino-1-phenyl- and 3-amino-1-(thien-2-yl)-4,4,4-trifluorobut-2-en-1-ones with 1,2-diaminopropane and 1,2-diamino-3,3,3-trifluoropropane

被引：9

作者：

Sosnovskikh, VY ^{[1
]}

Kutsenko, VA ^{[1
]}

Aizikovich, AY ^{[1
]}

Korotaev, VY ^{[1
]}

机构：

[1] AM Gorky Ural State Univ, Ekaterinburg 620083, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 1999年 / 48卷 / 11期

基金：

俄罗斯基础研究基金会;

关键词：

beta-amino-beta-trifluoromethylvinyl ketones; 1,2-diaminopropane; 1,2-diamino-3,3,3-trifluoropropane; 2,2,4-trisubstituted imidazolidines;

D O I：

10.1007/BF02494858

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of 3-amino-1-phenyl- and 3-amino-1-(thien-2-yl)-4,4,4-trifluorobut-2-en-1-ones with 1,2-diaminopropane under kinetically controlled conditions afford mixtures of cis and trans isomers of 2-aroylmethyl-4-methyl-2-trifluoromethylimidazolidines. Analogous reactions with 1,2-diamino-3,3,3-trifluoropropane yield cis-2-aroylmethyl-2,4-bis(trifluoromethyl)imidazolidines.

引用

页码：2112 / 2116

页数：5

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