Redox-active conjugated microporous polymers: a new organic platform for highly efficient energy storage

被引:238
作者
Xu, Fei [1 ,2 ]
Chen, Xiong [1 ]
Tang, Zhiwei [2 ]
Wu, Dingcai [2 ]
Fu, Ruowen [2 ]
Jiang, Donglin [1 ]
机构
[1] Natl Inst Nat Sci, Inst Mol Sci, Dept Mat Mol Sci, Okazaki, Aichi 4448787, Japan
[2] Sun Yat Sen Univ, Sch Chem & Chem Engn, Inst Mat Sci, PCFM Lab, Guangzhou 510275, Guangdong, Peoples R China
关键词
EXCEPTIONAL UPTAKE; SUPER-ABSORBENT; POROUS POLYMERS; FRAMEWORKS; FLUORESCENCE; SELECTIVITY; DEVICES; DESIGN; OXYGEN;
D O I
10.1039/c4cc01002g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Conjugated microporous polymers are developed as a new platform for lithium-battery energy storage, which features a near-unity coulombic efficiency, high capacity and cycle stability. The polymers exhibit synergistic structural effects on facilitating charge dynamics by virtue of their built-in redox skeletons, open nanopores and large surface areas.
引用
收藏
页码:4788 / 4790
页数:3
相关论文
共 39 条
[1]   Building better batteries [J].
Armand, M. ;
Tarascon, J. -M. .
NATURE, 2008, 451 (7179) :652-657
[2]   From a supramolecular tetranitrile to a porous covalent triazine-based framework with high gas uptake capacities [J].
Bhunia, Asamanjoy ;
Vasylyeva, Vera ;
Janiak, Christoph .
CHEMICAL COMMUNICATIONS, 2013, 49 (38) :3961-3963
[3]   Highly Efficient Activation of Molecular Oxygen with Nanoporous Metalloporphyrin Frameworks in Heterogeneous Systems [J].
Chen, Long ;
Yang, Yong ;
Guo, Zhaoqi ;
Jiang, Donglin .
ADVANCED MATERIALS, 2011, 23 (28) :3149-+
[4]   CMPs as Scaffolds for Constructing Porous Catalytic Frameworks: A Built-in Heterogeneous Catalyst with High Activity and Selectivity Based on Nanoporous Metalloporphyrin Polymers [J].
Chen, Long ;
Yang, Yong ;
Jiang, Donglin .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (26) :9138-9143
[5]   Light-Harvesting Conjugated Microporous Polymers: Rapid and Highly Efficient Flow of Light Energy with a Porous Polyphenylene Framework as Antenna [J].
Chen, Long ;
Honsho, Yoshihito ;
Seki, Shu ;
Jiang, Donglin .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (19) :6742-6748
[6]   Conjugated Microporous Polymers [J].
Cooper, Andrew I. .
ADVANCED MATERIALS, 2009, 21 (12) :1291-1295
[7]   Chemical functionalization strategies for carbon dioxide capture in microporous organic polymers [J].
Dawson, Robert ;
Cooper, Andrew I. ;
Adams, Dave J. .
POLYMER INTERNATIONAL, 2013, 62 (03) :345-352
[8]   Chemical tuning of CO2 sorption in robust nanoporous organic polymers [J].
Dawson, Robert ;
Adams, Dave J. ;
Cooper, Andrew I. .
CHEMICAL SCIENCE, 2011, 2 (06) :1173-1177
[9]   Synthetic control of the pore dimension and surface area in conjugated microporous polymer and copolymer networks [J].
Jiang, Jia-Xing ;
Su, Fabing ;
Trewin, Abbie ;
Wood, Colin D. ;
Niu, Hongjun ;
Jones, James T. A. ;
Khimyak, Yaroslav Z. ;
Cooper, Andrew I. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (24) :7710-7720
[10]   Conjugated microporous poly (aryleneethynylene) networks [J].
Jiang, Jia-Xing ;
Su, Fabing ;
Trewin, Abbie ;
Wood, Colin D. ;
Campbell, Nell L. ;
Niu, Hongjun ;
Dickinson, Calum ;
Ganin, Alexey Y. ;
Rosseinsky, Matthew J. ;
Khimyak, Yaroslav Z. ;
Cooper, Andrew I. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (45) :8574-8578