Solid-liquid equilibria for different heptanones with benzene, cyclohexane, and ethanol

被引：31

作者：

Fiege, C ^{[1
]}

Joh, R ^{[1
]}

Petri, M ^{[1
]}

Gmehling, J ^{[1
]}

机构：

[1] CARL VON OSSIETZKY UNIV, LEHRSTUHL TECH CHEM FB9, D-26111 OLDENBURG, GERMANY

来源：

JOURNAL OF CHEMICAL AND ENGINEERING DATA | 1996年 / 41卷 / 06期

关键词：

D O I：

10.1021/je960140h

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The liquidus lines of solid-liquid equilibria for the binary systems 2-heptanone, 3-heptanone, and 4-heptanone with benzene, cyclohexane, and ethanol were determined by means of the visual method. Furthermore enthalpies of fusion of the isomeric heptanones were measured with a Tian-Calvet calorimeter. The experimental SLE data were compared with those calculated from the modified UNIFAC (Dortmund) group contribution method.

引用

页码：1431 / 1433

页数：3

共 8 条

[1]

[Anonymous], 1963, RECENT PROGR MICROCA

[2] FROM UNIFAC TO MODIFIED UNIFAC TO PSRK WITH THE HELP OF DDB [J].

GMEHLING, J .

FLUID PHASE EQUILIBRIA, 1995, 107 (01) :1-29

[3] A MODIFIED UNIFAC MODEL .2. PRESENT PARAMETER MATRIX AND RESULTS FOR DIFFERENT THERMODYNAMIC PROPERTIES [J].

GMEHLING, J ;

LI, JD ;

SCHILLER, M .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1993, 32 (01) :178-193

[4] A DATA-BANK FOR AZEOTROPIC DATA - STATUS AND APPLICATIONS [J].

GMEHLING, J ;

MENKE, J ;

KRAFCZYK, J ;

FISCHER, K .

FLUID PHASE EQUILIBRIA, 1995, 103 (01) :51-76

[5]

Gmehling J., 1992, Thermodynamik, Vsecond

[6]

GMEHLING J, 1994, COMMUNICATION

[7] SOLID-LIQUID EQUILIBRIA IN BINARY-MIXTURES OF ORGANIC-COMPOUNDS [J].

JAKOB, A ;

JOH, R ;

ROSE, C ;

GMEHLING, J .

FLUID PHASE EQUILIBRIA, 1995, 113 (1-2) :117-126

[8]

WYNN NP, 1992, CHEM ENG PROG, V88, P52

← 1 →