Development of a chiral host system tunable via changes in a 21-column packing structure

被引:32
作者
Imai, Yoshitane
Kawaguchi, Kakuhiro
Sato, Tomohiro
Kuroda, Reiko
Matsubara, Yoshio
机构
[1] JST, ERATO, SORST, Kuroda Chiromorphol Team,Meguro Ku, Tokyo 1530041, Japan
[2] Kinki Univ, Fac Sci & Engn, Dept Appl Chem, Higashiosaka, Osaka 5778502, Japan
[3] Univ Tokyo, Grad Sch Arts & Sci, Dept Life Sci, Meguro Ku, Tokyo 1538902, Japan
关键词
chiral supramolecular complex; 2(1)-Column; molecular recognition; tunable host complex;
D O I
10.1016/j.tetlet.2006.09.011
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
A tunable chiral host system was developed by the self-assembly of a chiral 2(1)-column structure formed from (1R,2R)-1,2-diphenylethylenediamine and dicarboxylic acid. This host system can include guest molecules by changing the packing of a chiral 21-column enantioselectively. (c) 2006 Elsevier Ltd. All rights reserved.
引用
收藏
页码:7885 / 7888
页数:4
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