Gelcasting of aqueous mesocarbon microbead suspension

被引:21
作者
Li, F [1 ]
Ni, HJ
Wang, J
Sun, BD
Du, ZH
机构
[1] Shanghai Jiao Tong Univ, State Key Lab Met Matrix Composites, Sch Mat Sci & Engn, Shanghai 200030, Peoples R China
[2] Shanghai Jiao Tong Univ, Sch Mech & Power Energy Engn, Shanghai 200030, Peoples R China
[3] Nantong Inst Technol, Dept Mech Engn, Nantong 226007, Peoples R China
基金
中国博士后科学基金;
关键词
carbon microbeads; sintering; rheology; mechanical properties;
D O I
10.1016/j.carbon.2004.07.012
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Gelcasting, an in situ consolidation colloid forming process, is promising for the manufacture of structural ceramics with various shapes. In this case, the gelcasting process was adopted to obtain carbon artifacts with complex shapes. The mesocarbon microbead (MCMB) that has self-sintering property was chosen as the starting material. In order to optimize the MCMB suspensions for gel-casting the zeta potentials of MCMB particles dispersing in water and the rheological behaviors of MCMB suspensions were investigated. A stable MCMB suspension with solid loading up to 62.5 wt.% was prepared, from which uniform green body with complex shape was successfully gelcast. The performance of green bodies and sintered samples were measured and their microstructures were observed. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:2989 / 2995
页数:7
相关论文
共 22 条
  • [1] FORMATION OF MESOPHASE SPHERULES IN LOW-QL COAL-TAR PITCHES AND DEVELOPMENT OF MONOLITHIC CARBONS THEREFROM
    BHATIA, G
    AGGARWAL, RK
    PUNJABI, N
    BAHL, OP
    [J]. JOURNAL OF MATERIALS SCIENCE, 1994, 29 (18) : 4757 - 4763
  • [2] Densification of unidirectional C/C composites by melted pitch impregnation
    Granda, M
    Patrick, JW
    Walker, A
    Casal, E
    Bermejo, J
    Menendez, R
    [J]. CARBON, 1998, 36 (7-8) : 943 - 952
  • [3] Effect of particle size on gelcasting process and green properties in alumina
    Ha, CG
    Jung, YG
    Kim, JW
    Jo, CY
    Paik, U
    [J]. MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2002, 337 (1-2): : 212 - 221
  • [4] Strength improvement by densification of C/C composites
    Hatta, H
    Suzuki, K
    Shigei, T
    Somiya, S
    Sawada, Y
    [J]. CARBON, 2001, 39 (01) : 83 - 90
  • [5] CARBONACEOUS MESOPHASE - HISTORY AND PROSPECTS
    HONDA, H
    [J]. CARBON, 1988, 26 (02) : 139 - 156
  • [6] Processing of an aqueous tape casting of mesocarbon microbeads for high-performance carbonaceous laminations
    Hu, XB
    Zhong, S
    Zhao, BY
    Hu, KA
    [J]. CARBON, 2003, 41 (12) : 2285 - 2293
  • [7] Jenny M A, 1992, U.S. Patent, Patent No. [5,145,908, 5145908]
  • [8] KLETT JW, 2002, Patent No. 6491891
  • [9] A novel modified NiO cathode for molten carbonate fuel cells
    Li, F
    Chen, HY
    Wang, CM
    Hu, KA
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2002, 531 (01): : 53 - 60
  • [10] MARIA JP, 1995, CERAMIC ENG SCI P, V16, P1072