Strong magnetic exchange coupling in the cyano-bridged coordination clusters [(PY5Me2)4V4M(CN)6]5+ (M = Cr, Mo)

被引：45

作者：

Freedman, Danna E. ^{[1
]}

Jenkins, David M. ^{[1
]}

Long, Jeffrey R. ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 32期

关键词：

SINGLE-MOLECULE-MAGNET; HEPTANUCLEAR HETEROBIMETALLIC COMPLEXES; HIGH-SPIN MOLECULES; ORDERING TEMPERATURE; BUILDING-BLOCKS; PRUSSIAN BLUE; GROUND-STATE; VANADIUM(II); ANISOTROPY; TRINUCLEAR;

D O I：

10.1039/b908736b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reaction of [(PY5Me(2))V(MeCN)](2+) with [M(CN)(6)](3-) (M = Cr, Mo) affords the star-like clusters [(PY5Me(2))(4)V4M(CN)(6)](5+), exhibiting S = 9/2 ground states that are exceptionally well-isolated in energy.

引用

页码：4829 / 4831

页数：3

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