The role of neighbouring group participation in TTF-mediated 'radical-polar crossover' reactions:: trapping of aliphatic radicals by TTF+•

被引：25
作者：
Bashir, N [1 ]
Murphy, JA [1 ]
机构：
[1] Univ Strathclyde, Dept Pure & Appl Chem, Glasgow G1 1XL, Lanark, Scotland
来源：
CHEMICAL COMMUNICATIONS | 2000年 / 07期
关键词：
D O I：
10.1039/b000786m
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Trapping of secondary alkyl radicals with tetrathiafulvalenium tetrafluoroborate (TTF+.BF4-) leads to S-alkyltetrathiafulvalenium tetrafluoroborate salts; the solvolysis of such salts is critically dependent on the presence of appropriately sited neighbouring groups.
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收藏
页码：627 / 628
页数：2
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