共 31 条
Synthesis of mesoporous hexagonal boron nitride fibers with high surface area for efficient removal of organic pollutants
被引:77
作者:
Xue, Lili
[1
]
Lu, Binzeng
[1
]
Wu, Zhong-Shuai
[2
]
Ge, Chunhua
[1
]
Wang, Ping
[1
]
Zhang, Rui
[1
]
Zhang, Xiang-Dong
[1
]
机构:
[1] Liaoning Univ, Coll Chem, Shenyang 110036, Peoples R China
[2] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
基金:
中国国家自然科学基金;
关键词:
Boron nitride;
Synthesis;
Fiber;
Mesoporous;
Organic pollutants;
ACTIVATED CARBON;
METHYLENE-BLUE;
BASIC DYE;
NANOTUBES;
ADSORPTION;
D O I:
10.1016/j.cej.2014.01.033
中图分类号:
X [环境科学、安全科学];
学科分类号:
08 ;
0830 ;
摘要:
Developing advanced sorbent materials for effective removal of organic pollutants from water is of critical importance for environmental and water source protection. Here we reported the facile synthesis of hexagonal boron nitride (h-BN) fibers for efficient removal of methylene blue (MB) from water. The h-BN fibers was prepared by a combined sol-gel and temperature-controlled pyrolysis procedure in a N-2 atmosphere, using boron acid and melamine as the precursors. The as-prepared fibers showed long fibrous morphology (from several to tens of micrometers), high specific surface area (similar to 627 m(2)/g), mesoporous (3-4 nm) structure. Benefiting from these advantageous features, the resulting h-BN fibers exhibited a fast adsorption rate for MB (C/C-0 <9% within 10 min), a large adsorption capacity of similar to 631 m(2)/g, high separation selectivity that can fast adsorb MB from a mixed aqueous solution of MB and CuSO4, easy regeneration by simple heating in air, and excellent recyclability. These results demonstrate the great potential of mesoporous h-EN fibers for water purification and treatment. (C) 2014 Elsevier B.V. All rights reserved.
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页码:494 / 499
页数:6
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