A novel polymer-supported arene-ruthenium complex for ring-closing olefin metathesis

被引：0

作者：

Akiyama, R ^{[1
]}

Kobayashi, S ^{[1
]}

机构：

[1] Univ Tokyo, Grad Sch Pharmaceut Sci, Japan Sci & Technol Corp, CREST,Bunkyo Ku, Tokyo 1130033, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2002年 / 41卷 / 14期

关键词：

alkenes; metathesis; microencapsulation; ruthenium; supported catalysts;

D O I：

10.1002/1521-3773(20020715)41:14<2602::AID-ANIE2602>3.0.CO;2-3

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Styrene as ligand and support: An excellent polymer-supported ruthenium catalyst 1 has been developed in which the benzene rings of polystyrene are utilized as ligands to immobilize the ruthenium onto the polymer. In the presence of 1, ring-closing olefin metathesis proceeded smoothly to afford adducts in high yields. Furthermore, the catalyst was recovered quantitatively by filtration, and could be reused without loss of activity.

引用

页码：2602 / +

页数：4

共 44 条

[1] A recyclable 'boomerang' polymer-supported ruthenium catalyst for olefin metathesis [J].