Supramolecular self-assembled multilayers of terpyridine-functionalized perylene bisimide metal complexes

被引：43

作者：

Tuccitto, N. ^{[2
]}

Delfanti, I. ^{[2
]}

Torrisi, V. ^{[2
]}

Scandola, F. ^{[1
]}

Chiorboli, C. ^{[1
]}

Stepanenko, V. ^{[3
]}

Wuerthner, F. ^{[3
]}

Licciardello, A. ^{[2
]}

机构：

[1] Univ Ferrara, Dipartimento Chim, I-44100 Ferrara, Italy

[2] Univ Catania, Dipartimento Sci Chim, I-95125 Catania, Italy

[3] Univ Wurzburg, Inst Organ Chem, D-97074 Wurzburg, Germany

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2009年 / 11卷 / 20期

关键词：

ORGANIZED ASSEMBLIES; THIOL-TERPYRIDINE; GOLD; CHEMISTRY; SURFACES; RUTHENIUM(II); POLYMERS; DYNAMICS; ENERGY; FILMS;

D O I：

10.1039/b819711n

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

A terpyridine-functionalized perylene bisimide chromophore (TPBI) has been used as a building block in the stepwise, layer-by-layer fabrication of self-assembled Fe-TPBI multilayers on gold, with the assembled supramolecular chains oriented approximately perpendicular to the gold surface. Time-resolved spectroscopy measurements seem to indicate that the energy absorbed by the multilayer is promptly dissipated to the gold surface by ultrafast processes.

引用

页码：4033 / 4038

页数：6

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