Borinic Acid Catalyzed 1,2-cis-Stereoselective Glycosylations and Their Applications to the Total Synthesis of Natural Products

被引：3
|
作者：
Takahashi, Daisuke [1 ]
机构：
[1] Keio Univ, Fac Sci & Technol, Dept Appl Chem, Kohoku Ku, 3-14-1 Hiyoshi, Yokohama, Kanagawa 2238522, Japan
来源：
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN | 2018年 / 76卷 / 05期
基金：
日本学术振兴会;
关键词：
glycosylation; 1,2-cis-glycoside; borinic acid; stereoselective; natural glycolipid; CHARACTERISTIC GLYCOLIPID STRUCTURE; FUNGUS ACREMONIUM-STRICTUM; SIGNAL MODULATOR; GLYCOSPHINGOLIPIDS; ACREMOMANNOLIPIN; DERIVATIVES; ESTER;
D O I：
10.5059/yukigoseikyokaishi.76.470
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In this mini-review article, di (4-fluoro)phenylborinic acid (3c) catalyzed 1,2-cis-alpha and beta-stereoselective glycosylations using 1,2-anhydroglucose donor 8 and 1,2-anhydromannose donor 11, respectively, that have recently been developed in our laboratory, are introduced. In addition, representative applications of these glycosylation methods to the stereoselective synthesis of biologically active natural products, GSL-1 and acremomannolipin A, are also introduced.
引用
收藏
页码：470 / 473
页数：4
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