Electronic structure of light-induced lophyl radical derived from a novel hexaarylbiimidazole with π-conjugated chromophore

被引：38

作者：

Kikuchi, A ^{[1
]}

Iyoda, T ^{[1
]}

Abe, J ^{[1
]}

机构：

[1] Tokyo Metropolitan Univ, Grad Sch Engn, Dept Appl Chem, Tokyo 1920397, Japan

来源：

CHEMICAL COMMUNICATIONS | 2002年 / 14期

关键词：

D O I：

10.1039/b203814e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel photochromic hexaarylbiimidazole with a bithienyl group as an extended pi-conjugation unit was synthesized and the light-induced lophyl radical was found to be stabilized due to the delocalization of an unpaired electron, and to strongly absorb near-infrared light.

引用

页码：1484 / 1485

页数：2

共 17 条

[1]

Abe J, 2001, ANGEW CHEM INT EDIT, V40, P580, DOI 10.1002/1521-3773(20010202)40:3<580::AID-ANIE580>3.0.CO

[2]

2-8

[3] ESR STUDY OF LOPHYL FREE-RADICALS IN DRY FILMS [J].